سامانه پشتیبانی خدمات اطلاعات

  اخبار و اعلانات

 آمار

تعداد نشریات161
تعداد شماره‌ها6,468
تعداد مقالات69,896
تعداد مشاهده مقاله122,418,156
تعداد دریافت فایل اصل مقاله95,662,911
Zamani, Cyrus, Mohajerani, Seyed Sepehr, Ataie, Abolghasem. (1398). Synthesis of Three - Dimensional Mesoporous Silicon from Rice Husk via SHS Route. , 52(2), 149-153. doi: 10.22059/jufgnsm.2019.02.03
Cyrus Zamani; Seyed Sepehr Mohajerani; Abolghasem Ataie. "Synthesis of Three - Dimensional Mesoporous Silicon from Rice Husk via SHS Route". , 52, 2, 1398, 149-153. doi: 10.22059/jufgnsm.2019.02.03
Zamani, Cyrus, Mohajerani, Seyed Sepehr, Ataie, Abolghasem. (1398). 'Synthesis of Three - Dimensional Mesoporous Silicon from Rice Husk via SHS Route', , 52(2), pp. 149-153. doi: 10.22059/jufgnsm.2019.02.03
Zamani, Cyrus, Mohajerani, Seyed Sepehr, Ataie, Abolghasem. Synthesis of Three - Dimensional Mesoporous Silicon from Rice Husk via SHS Route. , 1398; 52(2): 149-153. doi: 10.22059/jufgnsm.2019.02.03

Synthesis of Three - Dimensional Mesoporous Silicon from Rice Husk via SHS Route

Journal of Ultrafine Grained and Nanostructured Materials
مقاله 3، دوره 52، شماره 2، اسفند 2019، صفحه 149-153    اصل مقاله (961.55 K)
نوع مقاله: Research Paper
شناسه دیجیتال (DOI): 10.22059/jufgnsm.2019.02.03
نویسندگان
Cyrus Zamani* ؛ Seyed Sepehr Mohajerani؛ Abolghasem Ataie
School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, Tehran, Iran.
چکیده
Silicon nanoparticles are the focus of attention thanks to their potentialities in advanced applications such as new batteries, photovoltaic cells and so on. The need to porous silicon is thus rising and will follow the same trend. In this work, highly porous nanostructured silicon is synthesized via Self-propagating high-temperature synthesis (SHS) route. Microstructural and phase analyses show that the employed technique is capable of producing a three-dimensional porous silicon which can act as a skeleton for embedding lithium ions and therefore, resisting large volume expansions arising during lithiation phase. Considering the fact that the wave front experiences high temperatures (above 1900°C) which can result in nanoparticles’ sintering, and in order to improve the porosity level, ammonium nitrate is used as a neutral additive at Mg/SiO2/NH4NO3 (2.4:1:0.1) molar ratio. The influence of nitrate addition on the final microstructure is studied through comparing salt-added samples with bare ones. Results show that ammonium nitrate can hinder the agglomeration of silicon nanoparticles during the progress of combustion wave thus affecting the specific surface area significantly (138.3 m2 g-1 as compared to for the 43.8 m2 g-1 for the reference sample which lacks NH4NO3). On the other hand, it was found that the added salt does not affect the product purity as examined through X-ray diffraction analysis.
کلیدواژه‌ها
Mesoporous Silicon؛ SHS؛ Rice Husk؛ Silica Nanoparticles؛ Lithium-ion Battery
مراجع

1. Alvarez J, Lopez G, Amutio M, Bilbao J, Olazar M. Upgrading the rice husk char obtained by flash pyrolysis for the production of amorphous silica and high quality activated carbon. Bioresource Technology. 2014;170:132-7.

2. Soltani N, Bahrami A, Pech-Canul MI, González LA. Review on the physicochemical treatments of rice husk for production of advanced materials. Chemical Engineering Journal. 2015;264:899-935.

3. Sun L, Gong K. Silicon-Based Materials from Rice Husks and Their Applications. Industrial & Engineering Chemistry Research. 2001;40(25):5861-77.

4. Wang W, Martin JC, Fan X, Han A, Luo Z, Sun L. Silica Nanoparticles and Frameworks from Rice Husk Biomass. ACS Applied Materials & Interfaces. 2012;4(2):977-81.

5. Jung DS, Ryou MH, Sung YJ, Park SB, Choi JW. Recycling rice husks for high-capacity lithium battery anodes. Proceedings of the National Academy of Sciences. 2013;110(30):12229-34.

6. An W, Gao B, Mei S, Xiang B, Fu J, Wang L, et al. Scalable synthesis of ant-nest-like bulk porous silicon for high-performance lithium-ion battery anodes. Nature Communications. 2019;10(1).

7. Zhao S, Xu Y, Xian X, Liu N, Li W. Fabrication of Porous Si@C Composites with Core-Shell Structure and Their Electrochemical Performance for Li-ion Batteries. Batteries. 2019;5(1):27.

8. Gao P, Tang H, Xing A, Bao Z. Porous silicon from the magnesiothermic reaction as a high-performance anode material for lithium ion battery applications. Electrochimica Acta. 2017;228:545-52.

9. Xakalashe BS, Tangstad M. Silicon processing: from quartz to crystalline silicon solar cells.

Sothern African Pyrometallurgy. 2011; 83-100.

10. Larbi KK, Barati M, McLean A. Reduction behaviour of rice husk ash for preparation of high purity silicon. Canadian Metallurgical Quarterly. 2011;50(4):341-9.

11. Liu PS, Chen GF. Applications of Porous Ceramics. Porous Materials: Processing and Applications, Elsevier Science & Technology, 1st edition. 2014.

12. Azadeh M, Zamani C, Ataie A, Morante JR. Three-dimensional rice husk-originated mesoporous silicon and its electrical properties. Materials Today Communications. 2018;14:141-50.

13. Liu N, Huo K, McDowell MT, Zhao J, Cui Y. Rice husks as a sustainable source of nanostructured silicon for high performance Li-ion battery anodes. Scientific Reports. 2013;3(1).

14. Bao Z, Weatherspoon MR, Shian S, Cai Y, Graham PD, Allan SM, et al. Chemical reduction of three-dimensional silica micro-assemblies into microporous silicon replicas. Nature. 2007;446(7132):172-5.

آمار
تعداد مشاهده مقاله: 1,018
تعداد دریافت فایل اصل مقاله: 683


سامانه مدیریت نشریات علمی. قدرت گرفته از سیناوب