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Mn-Metal Organic Framework as Heterogenous Catalyst for Oxidation of Alkanes and Alkenes | ||
| Journal of Sciences, Islamic Republic of Iran | ||
| مقاله 3، دوره 27، شماره 1، فروردین 2016، صفحه 31-37 اصل مقاله (267.95 K) | ||
| نوع مقاله: Final File | ||
| نویسندگان | ||
| F. Farzaneh* ؛ L. Hamidipour | ||
| Department of Chemistry, Faculty of Physics and Chemistry, Alzahra University, P.O.Box 1993891176, Vanak,Tehran, Islamic Republic of Iran | ||
| چکیده | ||
| Manganese metal-organic framework (Mn-MOF) containing Mn2+ ions, benzenetricarboxylic acid (BTC) and N,N-dimethylformamid (DMF) was prepared and used as catalyst for oxidation of alkenes such as 1,1-diphenylethylene, trans-stilbene, cyclohexene, norbornene, styrene and cyclooctene to epoxides with 33-92% conversion and 75-100% selectivity and oxidation of alkanes such as fluorene, adamantane, ethylbenzene and diphenylmethane to alcohols or ketones with tert-butylhydroperoxide (TBHP) with 19-64% conversion and 80-100% selectivity. Study of the catalyst stability and reusability revealed that Mn-MOF behaves heterogeneously in the oxidation reactions. | ||
| کلیدواژه‌ها | ||
| Mn metal organic framework؛ Heterogeneous catalysis؛ Oxidation reactions؛ Akanes؛ Alkenes | ||
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