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Akbari, Zohreh, Babaei, Alireza, Ataie, Abolghasem. (1397). Effective enhancement of electrochemical properties of LSM oxygen electrode in SOCs by LNO nano-catalyst infiltration. , 51(1), 53-59. doi: 10.22059/jufgnsm.2018.01.07
Zohreh Akbari; Alireza Babaei; Abolghasem Ataie. "Effective enhancement of electrochemical properties of LSM oxygen electrode in SOCs by LNO nano-catalyst infiltration". , 51, 1, 1397, 53-59. doi: 10.22059/jufgnsm.2018.01.07
Akbari, Zohreh, Babaei, Alireza, Ataie, Abolghasem. (1397). 'Effective enhancement of electrochemical properties of LSM oxygen electrode in SOCs by LNO nano-catalyst infiltration', , 51(1), pp. 53-59. doi: 10.22059/jufgnsm.2018.01.07
Akbari, Zohreh, Babaei, Alireza, Ataie, Abolghasem. Effective enhancement of electrochemical properties of LSM oxygen electrode in SOCs by LNO nano-catalyst infiltration. , 1397; 51(1): 53-59. doi: 10.22059/jufgnsm.2018.01.07

Effective enhancement of electrochemical properties of LSM oxygen electrode in SOCs by LNO nano-catalyst infiltration

Journal of Ultrafine Grained and Nanostructured Materials
مقاله 6، دوره 51، شماره 1، شهریور 2018، صفحه 53-59    اصل مقاله (1.19 M)
نوع مقاله: Research Paper
شناسه دیجیتال (DOI): 10.22059/jufgnsm.2018.01.07
نویسندگان
Zohreh Akbari1؛ Alireza Babaei* 2؛ Abolghasem Ataie1
1School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, Tehran, Iran
2Assistant Professor, School of Metallurgy and Materials Engineering, Faculty of Engineering, University of Tehran
چکیده
In this paper, the effects of infiltration of La2NiO4 (LNO) as a mixed ionic and electronic conductor (MIEC) on the electrochemical performance of porous strontium doped lanthanum manganite (LSM) oxygen electrode of solid oxide cells, in the temperature ranges of 650-850 °C, is reported. XRD and FE-SEM results of the LNO sample calcined at 900 °C confirmed the formation of single phase LNO nanoparticles and uniform distribution of LNO into the porous LSM backbone with a mean particle size of 40 nm, respectively. To characterize the electrochemical behavior of half-cells, electrochemical impedance spectroscopy (EIS) measurement at temperature intervals of 50 °C was carried out. The LNO infiltrated LSM electrodes showed a noticeably decreased activation energy (from 130 to 103 kJ mol-1) and polarization resistance (from 26.2 to 2.5 Ωcm2 at 650 °C) under open circuit voltage (OCV) condition. Besides, the equivalent circuit (EC) modeling revealed that LNO addition has a major effect on the low frequency arc, which is attributed to the surface exchange mechanisms. Decreased amounts of activation energy and polarization resistance of the infiltrated LSM electrode compared to those for the pure one suggest that introduction of LNO nano-particles to the microstructure of LSM is a promising approach to achieve better electrochemical performance even in the low temperature of 650°C.
کلیدواژه‌ها
La2NiO4؛ Solid Oxide Cell؛ LSM؛ Electro Catalyst؛ Infiltration
مراجع

1. Jiang SP. Development of lanthanum strontium manganite perovskite cathode materials of solid oxide fuel cells: a review. Journal of Materials Science. 2008;43(21):6799-833.

2. Jiang SP. Challenges in the development of reversible solid oxide cell technologies: a mini review. Asia-Pacific Journal of Chemical Engineering. 2016;11(3):386-91.

3. Rayment C, Sherwin S. Introduction to fuel cell technology. Department of Aerospace and Mechanical Engineering, University of Notre Dame, Notre Dame, IN. 2003 May 2;46556:11-2.

4. Perovskite Oxide for Solid Oxide Fuel Cells. Fuel Cells and Hydrogen Energy: Springer US; 2009. 

5. Ni M, Leung M, Leung D. Technological development of hydrogen production by solid oxide electrolyzer cell (SOEC). International Journal of Hydrogen Energy. 2008;33(9):2337-54.

6. Brisse A, Schefold J, Zahid M. High temperature water electrolysis in solid oxide cells. International Journal of Hydrogen Energy. 2008;33(20):5375-82.

7.  Electrochemical Energy: CRC Press; 2015 2015/12/10.

8. Borowski M. Perovskites: structure, properties, and uses. Nova Science Publishers; 2010.

9. Babaei A, Zhang L, Liu E, Jiang SP. Performance and stability of La0.8Sr0.2MnO3 cathode promoted with palladium based catalysts in solid oxide fuel cells. Journal of Alloys and Compounds. 2011;509(14):4781-7.

10. Chen K, Ai N, Jiang SP. Performance and structural stability of Gd0.2Ce0.8O1.9 infiltrated La0.8Sr0.2MnO3 nano-structured oxygen electrodes of solid oxide electrolysis cells. International Journal of Hydrogen Energy. 2014;39(20):10349-58.

11. Chen K, Ai N, Jiang SP. Enhanced electrochemical performance and stability of (La,Sr)MnO3–(Gd,Ce)O2 oxygen electrodes of solid oxide electrolysis cells by palladium infiltration. International Journal of Hydrogen Energy. 2012;37(2):1301-10.

12. Wang W, Jiang S. A mechanistic study on the activation process of (La, Sr)MnO3 electrodes of solid oxide fuel cells. Solid State Ionics. 2006;177(15-16):1361-9.

13. Irvine JTS, Neagu D, Verbraeken MC, Chatzichristodoulou C, Graves C, Mogensen MB. Evolution of the electrochemical interface in high-temperature fuel cells and electrolysers. Nature Energy. 2016;1(1):15014.

14. Carpanese MP, Clematis D, Bertei A, Giuliano A, Sanson A, Mercadelli E, et al. Understanding the electrochemical behaviour of LSM-based SOFC cathodes. Part I — Experimental and electrochemical. Solid State Ionics. 2017;301:106-15.

15. Bertei A, Carpanese MP, Clematis D, Barbucci A, Bazant MZ, Nicolella C. Understanding the electrochemical behaviour of LSM-based SOFC cathodes. Part II - Mechanistic modelling and physically-based interpretation. Solid State Ionics. 2017;303:181-90.

16. Vohs JM, Gorte RJ. High-Performance SOFC Cathodes Prepared by Infiltration. Advanced Materials. 2009;21(9):943-56.

17. Ding D, Li X, Lai SY, Gerdes K, Liu M. Enhancing SOFC cathode performance by surface modification through infiltration. Energy & Environmental Science. 2014;7(2):552.

18. Seyed-Vakili SV, Babaei A, Ataie M, Heshmati-Manesh S, Abdizadeh H. Enhanced performance of La 0.8 Sr 0.2 MnO 3 cathode for solid oxide fuel cells by co-infiltration of metal and ceramic precursors. Journal of Alloys and Compounds. 2018;737:433-41.

19. Dailly J, Delrue A, Ancelin M, Marrony M. Nanoparticles Infiltration into SOFC Cathode Backbones. ECS Transactions. 2017;78(1):1979-91.

20. Egger A, Schrödl N, Gspan C, Sitte W. La2NiO4+δ as electrode material for solid oxide fuel cells and electrolyzer cells. Solid State Ionics. 2017;299:18-25.

21. Mauvy F, Lalanne C, Bassat JM, Grenier JC, Zhao H, Dordor P, et al. Oxygen reduction on porous Ln2NiO4+δ electrodes. Journal of the European Ceramic Society. 2005;25(12):2669-72.

22. Cetin D. Thermodynamic stability of perovskite and lanthanum nickelate-type cathode materials for solid oxide fuel cells(Doctoral dissertation).

23. Zhang X, Zhang H, Liu X. High performance La 2 NiO 4+δ -infiltrated (La 0.6 Sr 0.4 ) 0.995 Co 0.2 Fe 0.8 O 3−δ cathode for solid oxide fuel cells. Journal of Power Sources. 2014;269:412-7.

24. Zhang X, Li W, Guan B, Liu X. A-Site Deficient La2-XNiO4+δInfiltrated LSCF Cathode with Improved Performance and Stability. ECS Transactions. 2017;78(1):593-601.

25. Nicollet C, Flura A, Vibhu V, Rougier A, Bassat JM, Grenier JC. La 2 NiO 4+δ infiltrated into gadolinium doped ceria as novel solid oxide fuel cell cathodes: Electrochemical performance and impedance modelling. Journal of Power Sources. 2015;294:473-82.

26. Dong X, Wu Z, Chang X, Jin W, Xu N. One-Step Synthesis and Characterization of La2NiO4+δMixed-Conductive Oxide for Oxygen Permeation. Industrial & Engineering Chemistry Research. 2007;46(21):6910-5.

27. Paulus W, Cousson A, Dhalenne G, Berthon J, Revcolevschi A, Hosoya S, et al. Neutron diffraction studies of stoichiometric and oxygen intercalated La2NiO4 single crystals. Solid State Sciences. 2002;4(5):565-73.

28. Li N, Ai N, Chen K, Cheng Y, He S, Saunders M, et al. In situ assembled La0.8Sr0.2MnO3 cathodes on a Y2O3–ZrO2 electrolyte of solid oxide fuel cells – interface and electrochemical activity. RSC Advances. 2016;6(101):99211-9.

29. Perry Murray E. (La,Sr)MnO3–(Ce,Gd)O2−x composite cathodes for solid oxide fuel cells. Solid State Ionics. 2001;143(3-4):265-73.

30. Chen X. Electrochemical behavior of La(Sr)MnO3 electrode under cathodic and anodic polarization. Solid State Ionics. 2004;167(3-4):379-87.

31. Jiang SP, Zhang JP, Foger K. Deposition of Chromium Species at Sr-Doped LaMnO[sub 3] Electrodes in Solid Oxide Fuel Cells II. Effect on O[sub 2] Reduction Reaction. Journal of The Electrochemical Society. 2000;147(9):3195.

32. van Heuveln FH. Electrode Properties of Sr-Doped LaMnO[sub 3] on Yttria-Stabilized Zirconia. Journal of The Electrochemical Society. 1997;144(1):134.

33. van Heuveln FH. Electrode Properties of Sr-Doped LaMnO[sub 3] on Yttria-Stabilized Zirconia. Journal of The Electrochemical Society. 1997;144(1):126.

34. Jiang Z, Zhang L, Feng K, Xia C. Nanoscale bismuth oxide impregnated (La,Sr)MnO3 cathodes for intermediate-temperature solid oxide fuel cells. Journal of Power Sources. 2008;185(1):40-8.

35. Jiang Z, Zhang L, Cai L, Xia C. Bismuth oxide-coated (La,Sr)MnO3 cathodes for intermediate temperature solid oxide fuel cells with yttria-stabilized zirconia electrolytes. Electrochimica Acta. 2009;54(11):3059-65.

36. Zhang QS, Hirano A, Imanishi N, Takeda Y, Yamahara K. LSM Cathodes Infiltrated With Er[sub 2]O[sub 3] Stabilized Bi[sub 2]O[sub 3]. Journal of Fuel Cell Science and Technology. 2009;6(1):011001.

37. Ai N, Jiang SP, Lü Z, Chen K, Su W. Nanostructured (Ba,Sr)(Co,Fe)O[sub 3−δ] Impregnated (La,Sr)MnO[sub 3] Cathode for Intermediate-Temperature Solid Oxide Fuel Cells. Journal of The Electrochemical Society. 2010;157(7):B1033.

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