تعداد نشریات | 161 |
تعداد شمارهها | 6,532 |
تعداد مقالات | 70,504 |
تعداد مشاهده مقاله | 124,121,854 |
تعداد دریافت فایل اصل مقاله | 97,229,472 |
Deasphalting of Olefin Pyrolysis Fuel Oil by Combination of Chemical–Physical Methods | ||
Journal of Chemical and Petroleum Engineering | ||
مقاله 3، دوره 52، شماره 1، شهریور 2018، صفحه 23-33 اصل مقاله (877.25 K) | ||
نوع مقاله: Research Paper | ||
شناسه دیجیتال (DOI): 10.22059/jchpe.2018.239677.1207 | ||
نویسندگان | ||
Elham sadat Moosavi1؛ Mahtab Gharibi* 2؛ Ramin Karimzadeh3؛ Behnaz Asbaghi2؛ Soulmaz Sayedshahabi2؛ Sina Alizad3؛ Majid Zare3 | ||
1Chemical Engineering Department, Buein Zahra Technical University, Buein Zahra, Iran | ||
2National Petrochemical Company, Petrochemical Research and Technology Company -P.O. Box 1435884711, Tehran, Iran | ||
3Chemical Engineering Faculty, Tarbiat Modares University, P.O. Box 14155-4838, Tehran, Iran | ||
چکیده | ||
This work investigates the effect of different conditions of PFO thermal cracking from two PFO samples on liquid, solid and gas product yield and asphaltene removal efficiency in a new designed experimental setup. No need to use a catalyst, simple operating system and experiment conditions, the ability to use water as a cheap carrier gas and high asphaltene extraction efficiency without the use of solvents are outstanding benefits of this method to upgrade PFO. The yields of the liquid, solid and gas products were compared in various operating conditions and the optimum experimental conditions were obtained. The results revealed the best thermal cracking condition of PFO in terms of liquid yield and asphaltene removal in this setup for samples. The optimum conditions were 390 and 380 °C for reactor temperature of PFO-1 and PFO-2, respectively; 150 °C for temperature of carrier gas and 100 ml/min for carrier gas flow rate. In these circumstances about 70 and 53 wt% of the liquid product, 25 wt% of the solid products, and 5 wt% of the gas product are generated while the asphaltene separation was reached about 95 and 96.5%. | ||
کلیدواژهها | ||
asphaltene؛ Naphthalene؛ Product yield؛ Pyrolysis fuel oil (PFO)؛ Thermal cracking | ||
مراجع | ||
[1] Andersen, S. I. and Speight, J. G. (2001). "Petroleum resins: separation, character, and role in petroleum." Petroleum science and technol ogy , Vol. 19, No. 1, pp. 1 -34.
[2] Fan, T. and Buckley, J. S. (2002). "Rapid and accurate SARA analysis of medium gravity crude oils. " Energy & Fuels, Vol. 16. No. 6, pp. 1571 - 1575.
[3] Kord, S. and Ayatollahi, S. (2012). "Asphaltene precipitation in live crude oil during natural depletion: experimental investigation and modeling." Fluid Phase Equilibria Vol. 336, pp. 63–70.
[4] Leontaritis, K.J. and Mansoori, G.A. (1988). "Asphaltene deposition: a survey of field experiences and research approaches. " Journal of Petroleum Science Engineering, Vol. 1, No. 3, pp. 229 – 239.
[5] Mohammadi, A.H. and Richon, D. (2007). "A monodisperse thermodynamic model for estimating asphaltene precipitation. " AIChE Journal , Vol. 53, No. 11, pp. 2940 – 2947.
[6] Mullins, O., Sheu, E.Y. (1998). Structures and Dynamics of Asphaltenes , New York, Springer.
[7] Speight, J.G. (1991). The Chemistry and Technology of Petroleum , New York, CRC Press.
[8] Adebiyi, F.M. and Thoss, V. (2014). "Organic and elemental elucidation of asphaltene fraction of Nigerian crude oils. " Fue l, Vol. 118, pp. 426 –431.
[9] Yong-jun, L. (2012). "Microstructure characterization of asphaltenes from atmospheric residue before and after hydroprocessing." Journal of Fuel Chemistry and Technology, Vol. 40, No. 9, pp.1086−1091.
[10] Lababidi, H.M., Sabti, H. M. and AlHumaidan, F. S. (2014). "Changes in asphaltenes during thermal cracking of residual oils ." Fuel , Vol. 117, pp. 59 –67.
[11] Duyck, C., Miekeley, Silveira, C. L. P. and Szatmari, P. (2002). "Trace element determination in crude oil and its fractions by inductively coupled plasma mass spectrometry using ultrasonic nebulization of toluene solutions." Spectrochim Acta, Part B , Vol. 57, No. 12, pp. 1979 -1990.
[12] Park, S .J. and Mansoori, G. A. (1988). "Aggregation and Deposition of Heavy Organics in Petroleum Crudes." Energy Sources , Vol. 10, No. 2, pp.109 -125.
[13] Taylor, S.E. (1992). "Use of Surface -Tension Measurements to Evaluate Aggregation of Asphaltenes in Organic-Solvents. " Fuel , Vol. 71, pp. 1338 -1339.
[14] Thawer, R., Nicoll, D. C. A. and Dick, G. (1990). "Asphaltene Deposition in Production Facilities.” SPE Production Engineering ." Vol. 5, No. 4, pp. 475 -480.
[15] AlHumaidan, F., Lababidi, H. M. S. and Al Rabiah, H. (2013). "Thermal cracking kinetics of Kuwaiti vacuum residues in Eureka process. " Fuel , Vol. 103, pp. 923 – 931.
[16] Silva, F. B., Guimarães, M. J. O. C. Seidi, P. R. and Garica, M. E. F. (2013). "Extraction And Characterization (Compositional And Thermal) Of Asphaltenes From Brazilian Vacuum Residues." Brazilian Journa l of Petroleum and Gas , Vol. 7, No. 3, pp. 107 -118.
[17] Rana, M.S. andSámano, V., Ancheyta, J., Diaz, J.A.I. (2007). "A review of recent advances on process technologies for upgrading of heavy oils and residuaet. " Fuel , Vol. 86, pp.1216 -1231.
[18] Takatusuka, T., Watari, R. and Hayakawa, H. (1996). "Renewed attention to the EUREKA pro-cess: thermal cracking process and related tech nologies for residual oil upgrading. "Studies in Surface Science and Catalysis, Vol. 100, pp. 293 –301.
[19] Shishavan, R., Ghashghaee, M. and Karimzadeh, R. (2011). "Investigation of kinetics and cracked oil structural changes in thermal cracking of Iranian vacuum residues. " Fuel Processing Tech –nology , Vol. 92, No. 12, pp. 2226 – 2234.
[20] Fesharaki, M., Ghashghaee, M. and Karimzadeh, R. (2013). "Comparison of four nanoporous catalysts in thermocatalytic upgrading of vacuum residue." Journal of Analytical and Applied Pyrolysis, Vol. 102, pp. 97 -102.
[21] Sawarkar, A. N., Pandit, A. B., Samant, S. D. and Joshi, J. B. (2007). "Petroleum Residue Upgrading Via Delayed Coking: A Review." The Canadian Journal of Chemical Engineering , Vol. 85, No.1, pp. 1– 24.
[22] ASTM D3279, Standard Test Method for n-Heptane Insolubles, Book of Standards Volume: 04.03, West Conshohocken,2001.
[23] Kashirski, V.G. and Petelina, V.S. (2001). "Thermal decomposition of the Kenderlyk Oil shale under conditions of high -speed heating. " Oil Shale, Vol. 18, No. 1, pp. 85-91. | ||
آمار تعداد مشاهده مقاله: 715 تعداد دریافت فایل اصل مقاله: 912 |