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sajjadifar, sami, Masoudi, Pegah. (1397). Silica Boron Sulfonic Acid as Heterogeneous and Highly Efficient Solid Acid Catalyst For the Preparation of Hantzsch 1,4-dihydropyridines Under Solvent-Free. , 30(1), 33-40. doi: 10.22059/jsciences.2019.69630
sami sajjadifar; Pegah Masoudi. "Silica Boron Sulfonic Acid as Heterogeneous and Highly Efficient Solid Acid Catalyst For the Preparation of Hantzsch 1,4-dihydropyridines Under Solvent-Free". , 30, 1, 1397, 33-40. doi: 10.22059/jsciences.2019.69630
sajjadifar, sami, Masoudi, Pegah. (1397). 'Silica Boron Sulfonic Acid as Heterogeneous and Highly Efficient Solid Acid Catalyst For the Preparation of Hantzsch 1,4-dihydropyridines Under Solvent-Free', , 30(1), pp. 33-40. doi: 10.22059/jsciences.2019.69630
sajjadifar, sami, Masoudi, Pegah. Silica Boron Sulfonic Acid as Heterogeneous and Highly Efficient Solid Acid Catalyst For the Preparation of Hantzsch 1,4-dihydropyridines Under Solvent-Free. , 1397; 30(1): 33-40. doi: 10.22059/jsciences.2019.69630

Silica Boron Sulfonic Acid as Heterogeneous and Highly Efficient Solid Acid Catalyst For the Preparation of Hantzsch 1,4-dihydropyridines Under Solvent-Free

Journal of Sciences, Islamic Republic of Iran
مقاله 4، دوره 30، شماره 1، فروردین 2019، صفحه 33-40    اصل مقاله (171.84 K)
نوع مقاله: Note
شناسه دیجیتال (DOI): 10.22059/jsciences.2019.69630
نویسندگان
sami sajjadifar* ؛ Pegah Masoudi
Department of Chemistry, Payame Noor University, PO BOX 19395-4697 Tehran, Iran
چکیده
Silica boron sulfonic acid [SiO2–B(OSO3H)3] as an inexpensive, reusable, and Lewis and Brønsted acid catalyst was successfully synthesized, and used for the one-pot three-components synthesis of biologically active substituted Hantzsch 1,4-dihydropyridine derivatives  in the absence of solvent at 90ºC. Silica boron sulfonic acid is attractive and efficient, because it plays in two role as a Lewis acid (by boron atom) and also as a Brønsted acid (by OSO3H group), which can have a  better effect in reaction. The reaction was carried out under solvent-free and mild conditions. Silica boron sulfonic acid can be recovered and reused for at least five consecutive runs.
کلیدواژه‌ها
Lewis and Brønsted acidic؛ Hantzsch Reaction؛ 1,4-dihydropyridine؛ Solvent-free؛ One-pot condensation
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