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Shahbazi, Faezeh, Mohadesi, Majid. (1401). Experimental Investigation and Thermodynamic Modeling in Liquid-Liquid Equilibrium of Water + Propionic Acid + Cyclic Alcohols at T= 303.2, 313.2 and 323.2 K. , 56(1), 89-104. doi: 10.22059/jchpe.2022.333504.1371
Faezeh Shahbazi; Majid Mohadesi. "Experimental Investigation and Thermodynamic Modeling in Liquid-Liquid Equilibrium of Water + Propionic Acid + Cyclic Alcohols at T= 303.2, 313.2 and 323.2 K". , 56, 1, 1401, 89-104. doi: 10.22059/jchpe.2022.333504.1371
Shahbazi, Faezeh, Mohadesi, Majid. (1401). 'Experimental Investigation and Thermodynamic Modeling in Liquid-Liquid Equilibrium of Water + Propionic Acid + Cyclic Alcohols at T= 303.2, 313.2 and 323.2 K', , 56(1), pp. 89-104. doi: 10.22059/jchpe.2022.333504.1371
Shahbazi, Faezeh, Mohadesi, Majid. Experimental Investigation and Thermodynamic Modeling in Liquid-Liquid Equilibrium of Water + Propionic Acid + Cyclic Alcohols at T= 303.2, 313.2 and 323.2 K. , 1401; 56(1): 89-104. doi: 10.22059/jchpe.2022.333504.1371

Experimental Investigation and Thermodynamic Modeling in Liquid-Liquid Equilibrium of Water + Propionic Acid + Cyclic Alcohols at T= 303.2, 313.2 and 323.2 K

Journal of Chemical and Petroleum Engineering
دوره 56، شماره 1، شهریور 2022، صفحه 89-104    اصل مقاله (1.63 M)
نوع مقاله: Research Paper
شناسه دیجیتال (DOI): 10.22059/jchpe.2022.333504.1371
نویسندگان
Faezeh Shahbazi؛ Majid Mohadesi*
Department of Chemical Engineering, Faculty of Engineering, Kermanshah University of Technology, Kermanshah, Iran
چکیده
Recovery of propionic acid from aqueous solution is economically and environmentally important. In this study, the liquid-liquid equilibrium data of water + propionic acid + cyclic alcohols (cyclopentanol and cyclohexanol) ternary system was obtained at 303.2, 313.2, and 323.2 K temperatures. These ternary systems exhibit type-1 behavior of liquid-liquid equilibrium (LLE). The Hand and Bachman equations confirm the validity of the measured data. For correlation of liquid-liquid equilibrium data, the NRTL and UNIQUAC thermodynamic models have been used and the inter-molecular interactions coefficients have been determined. RMSD values for NRTL and UNIQUAC models in cyclopentanol containing systems were 0.0107 and 0.0057, respectively, for cyclohexanol 0.0108 and 0.0076 respectively, which showed the accuracy of these models in correlation liquid-liquid equilibrium data. The values of the selectivity factor for both solvents larger than the unit are obtained, which shows that these solvents can be used to extract propionic acid from aqueous solution.
کلیدواژه‌ها
Liquid Extraction؛ LLE؛ NRTL and UNIQUAC؛ Propionic Acid؛ Thermodynamic Models
مراجع
  1. Ghalami-Choobar B, Ghanadzadeh A, Kousarimehr S. Salt effect on the liquid-liquid equilibrium of (water+ propionic acid+ cyclohexanol) system at T=(298.2, 303.2, and 308.2) K. Chinese Journal of Chemical Engineering. 2011; 19(4): 565-9.
  2. Theodore L, Ricci F. Mass transfer operations for the practicing engineer. John Wiley & Sons; 2011.
  3. Luo L, Liu D, Li L, Chen Y. Phase equilibria of (water+ propionic acid or butyric acid+ 2-methoxy-2-methylpropane) ternary systems at 298.2 K and 323.2 K. Fluid Phase Equilibria. 2015; 403: 30-5.
  4. Özmen D. (Liquid+ liquid) equilibria of (water+ propionic acid+ methyl isoamyl ketone or diisobutyl ketone or ethyl isoamyl keton) at T= 298.2 K. Fluid phase equilibria. 2006; 250(1-2): 70-5.
  5. Özmen D. (Liquid+ liquid) equilibria of (water+ propionic acid+ dipropyl ether or diisopropyl ether) at T= 298.2 K. The Journal of Chemical Thermodynamics. 2007; 39(1): 123-7.
  6. Bilgin M, Arısoy Ç. Liquid phase equilibria of (water+ propionic acid+ oleyl alcohol) ternary system at several temperatures. Fluid phase equilibria. 2006; 250(1-2): 59-63.
  7. Ghanadzadeh H, Ghanadzadeh A, Bahrpaima K, Saadat SS. (Liquid+ liquid) equilibria of (water+ propionic acid+ 2-ethyl-1-hexanol): Experimental data and correlation. The Journal of Chemical Thermodynamics. 2008; 40(5): 879-84.
  8. Gilani AG, Gilani HG, Saadat SL, Nasiri-Touli E, Peer M. Liquid-liquid equilibrium data in aqueous solutions of propionic and butyric acids with 1-heptanol at T=(298.15, 308.15, and 318.15) K. Korean Journal of Chemical Engineering. 2016; 33(4): 1408-15.
  9. Mohsen-Nia M, Jazi B, Amiri H. Binodal curve measurements for (water+ propionic acid+ dichloromethane) ternary system by cloud point method. The Journal of Chemical Thermodynamics. 2009; 41(7): 859-63.
  10. Chen Y, Wang Y, Zhou S, Chen H, Liu D, Li L. Liquid phase equilibrium of the ternary systems, water+ propionic or butyric acid+ mesityl oxide, at (298.2 and 323.2) K. The Journal of Chemical Thermodynamics. 2017; 111: 72-9.
  11. Çehreli S, Gündogdu T. Phase equilibria of (water–carboxylic acid–diethyl maleate) ternary liquid systems at 298.15 K. Fluid Phase Equilibria. 2011; 303(2): 168-73.
  12. Harrison PT. Propionic acid and the phenomenon of rodent forestomach tumorigenesis: a review. Food and chemical toxicology. 1992; 30(4): 333-40.
  13. Henschel R, Agathos M, Breit R. Acute irritant contact dermatitis from propionic acid used in animal feed preservation. Contact dermatitis. 1999; 40(6): 328.
  14. Özmen D, Dramur U, Tatli B. Liquid-liquid equilibria of propionic acid-water-solvent (n-hexane, cyclohexane, cyclohexanol and cyclohexyl acetate) ternaries at 298.15 K. Brazilian Journal of Chemical Engineering. 2004; 21(4): 647-57.
  15. Çehreli S, Özmen D, Tatlı B. (Liquid+ liquid) equilibria of (water+ propionic acid+ diethyl phthalate) at several temperatures. The Journal of Chemical Thermodynamics. 2005; 37(10): 1144-50.
  16. Kırbaşlar Şİ, Şahin S, Bilgin M. (Liquid+ liquid) equilibria of (water+ propionic acid+ diethyl succinate or diethyl glutarate or diethyl adipate) ternary systems. The Journal of Chemical Thermodynamics. 2007; 39(11): 1463-9.
  17. Çehreli S, Tatlí B, Bagˇman P. (Liquid+ liquid) equilibria of (water+ propionic acid+ cyclohexanone) at several temperatures. The Journal of Chemical Thermodynamics. 2005; 37(12): 1288-93.
  18. Hashemi S, Ghotbi C, Taghikhani VA, Behzadi B. Application of quasi-chemical models to liquid–liquid equilibrium calculations for ternary systems containing water, propionic acid and organic solvents. Fluid phase equilibria. 2004; 226: 251-9.
  19. Othmer DF, White RE, Trueger E. Liquid-liquid extraction data. Industrial & Engineering Chemistry. 1941; 33(10): 1240-8.
  20. Özmen D, Çehreli S, Dramur U. (Liquid+ liquid) equilibria of (water+ propionic acid+ dimethyl phthalate) at several temperatures. The Journal of Chemical Thermodynamics. 2005; 37(8): 837-42.
  21. Bekri S, Özmen D, Özmen A. Correlation of experimental liquid–liquid equilibrium data for ternary systems using NRTL and GMDH-type neural network. Journal of Chemical & Engineering Data. 2017; 62(6): 1797-805.
  22. Renon H, Prausnitz JM. Local compositions in thermodynamic excess functions for liquid mixtures. AIChE journal. 1968; 14(1): 135-44.
  23. Abrams DS, Prausnitz JM. Statistical thermodynamics of liquid mixtures: a new expression for the excess Gibbs energy of partly or completely miscible systems. AIChE Journal. 1975; 21(1): 116-28.
  24. Chen N, Xu D, Gao J, Zhang L, Zhang K, Guan D. Measurement and correlation of phase equilibria for isobutyl acetate+{ethanol or methanol}+ water at 303.15 and 323.15 k. Journal of Chemical & Engineering Data. 2017; 62(5): 1587-93.
  25. Toikka M, Trofimova D, Samarov A. Liquid-liquid equilibrium and critical states for the quaternary system propionic acid–n-butanol–n-butyl propionate–water at 303.15 K. Fluid Phase Equilibria. 2018; 460: 17-22.
  26. Fredenslund A, Jones RL, Prausnitz JM. Group‐contribution estimation of activity coefficients in nonideal liquid mixtures. AIChE Journal. 1975; 21(6): 1086-99.
  27. Ghanadzadeh H, Gilani AG, Bahrpaima K, Sariri R. (Liquid+ liquid) equilibria for ternary mixtures of (water+ propionic acid+ organic solvent) at T= 303.2 K. The Journal of Chemical Thermodynamics. 2010; 42(2): 267-73.
  28. Gündogdu T, Çehreli S. Ternary liquid–liquid phase equilibria of (water–carboxylic acid–1-undecanol) systems at 298.15 K. Fluid phase equilibria. 2012; 331: 26-32.
  29. Zhu Z, Bai W, Xu Y, Gong H, Wang Y, Xu D, Gao J. Liquid-liquid extraction of methanol from its mixtures with hexane using three imidazolium-based ionic liquids. The Journal of Chemical Thermodynamics. 2019; 138: 189-95.
  30. Samarov A, Toikka M, Trofimova M, Toikka A. Liquid-liquid equilibrium for the quaternary system propionic acid+ n-propanol+ n-propyl propionate+ water at 293.15, 313.15 and 333.15 K. Fluid Phase Equilibria. 2016; 425: 183-7.
  31. Yang C, Qian Y, Guo J, Chen J. Liquid–liquid equilibria for the ternary system methyl isobutyl ketone+ 1, 2-benzenediol+ water. Journal of Chemical & Engineering Data. 2014; 59(11): 3663-7.
  32. Ghanadzadeh H, Ghanadzadeh A, Moein M, Shekarsaraee S, Jamshidi Y. Binodal curves and tie line data of the water–propionic acid–iso-butyl acetate at T=(298.2, 308.2, 318.2, and 328.2) K. Thermochimica acta. 2012; 540: 116-22.
  33. Behroozi M, Armozd P, Badieh MM. Determination of liquid–liquid equilibria data for (water+ propanoic acid+ 3-methylbutan-1-ol) ternary mixture at 293.15 K to 313.15 K. Journal of Molecular Liquids. 2017; 243: 513-8.
  34. Çehreli S. Liquid–liquid equilibria of ternary systems (water+ carboxylic acid+ cumene) at 298.15 K. Fluid phase equilibria. 2006; 248(1): 24-8.
  35. Bilgin M, Birman İ. Separation of propionic acid by diethyl carbonate or diethyl malonate or diethyl fumarate and the synergistic effect of phosphorus compounds and amines. Fluid phase equilibria. 2010; 292(1-2): 13-9.
  36. Kırbaşlar Şİ, Şahin S, Bilgin M. (Liquid+ liquid) equilibria of (water+ propionic acid+ alcohol) ternary systems. The Journal of Chemical Thermodynamics. 2006; 38(12): 1503-9.
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