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Li, C.L., Wang, S., Ji, F., Zhang, J.J., Wang, L.C.. (1393). Thermodynamics ofCu2+Adsorption on soilHumin. , 9(1), 43-52. doi: 10.22059/ijer.2015.872
C.L. Li; S. Wang; F. Ji; J.J. Zhang; L.C. Wang. "Thermodynamics ofCu2+Adsorption on soilHumin". , 9, 1, 1393, 43-52. doi: 10.22059/ijer.2015.872
Li, C.L., Wang, S., Ji, F., Zhang, J.J., Wang, L.C.. (1393). 'Thermodynamics ofCu2+Adsorption on soilHumin', , 9(1), pp. 43-52. doi: 10.22059/ijer.2015.872
Li, C.L., Wang, S., Ji, F., Zhang, J.J., Wang, L.C.. Thermodynamics ofCu2+Adsorption on soilHumin. , 1393; 9(1): 43-52. doi: 10.22059/ijer.2015.872

Thermodynamics ofCu2+Adsorption on soilHumin

International Journal of Environmental Research
مقاله 6، دوره 9، شماره 1، فروردین 2015، صفحه 43-52    اصل مقاله (393.64 K)
نوع مقاله: Original Research Paper
شناسه دیجیتال (DOI): 10.22059/ijer.2015.872
نویسندگان
C.L. Li1؛ S. Wang2؛ F. Ji1؛ J.J. Zhang* 1؛ L.C. Wang3
1College of Resource and Environmental Science, Jilin Agricultural University, Changchun, 130118,P.R. China
2College of Plant Science, Jilin Agricultural Science and Technology College, Jilin, 132101, P.R. China
3Institute of Agricultural Resources and Environments, Jilin Academy of Agricultural Sciences, Changchun, 130124, P.R. China
چکیده
The adsorption thermodynamic characteristic of Cu2+ from aqueous solution onto humin and
also humic acid from a typical black soil in northeast China were examined at three different temperatures
(298, 318 and 338 K) by batch isotherm experiments. Results showed that humin was structurally different
from humic acid. The increase of temperature had a positive effect on the adsorption process. Freundlich
equation described the equilibrium data better with respect to Langmuir equation. Thermodynamic parameters,
i.e. standard free energy changes (ΔGº), standard enthalpy change (ΔHº) and standard entropy change (ΔSº),
revealed that Cu2+ adsorption by humin and humic acid were a feasible, spontaneous and endothermic process
with an increase in disorder. The values of isosteric heat of adsorption (ΔHx) increased with increasing surface
Cu2+ loading, and the increase in ΔHx values was smaller for humin than for humic acid. The results indicated
that humin and humic acid possessed energetically heterogeneous surfaces. Humic acid had greater surface
heterogeneity than humin
کلیدواژه‌ها
Humin؛ Humic Acid؛ Cu2+؛ Adsorption Isotherm؛ Thermodynamic parameters
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