پیوندهای مفید
اخبار و اعلانات
آمار
| تعداد نشریات | 161 |
| تعداد شمارهها | 6,532 |
| تعداد مقالات | 70,501 |
| تعداد مشاهده مقاله | 124,092,259 |
| تعداد دریافت فایل اصل مقاله | 97,196,137 |
Use of Eggshell as a Low-Cost Alternative Adsorbent for Elimination of Fluoride from Groundwater | ||
| Pollution | ||
| دوره 9، شماره 1، فروردین 2023، صفحه 39-55 اصل مقاله (1.94 M) | ||
| نوع مقاله: Original Research Paper | ||
| شناسه دیجیتال (DOI): 10.22059/poll.2022.341026.1425 | ||
| نویسندگان | ||
| Zakaria Assami* 1؛ Amar Messaitfa2 | ||
| 1Laboratory of Water Engineering and Environment within the Saharian milieu, Department of Hydraulic and Civil Engineering, Faculty of Applied Sciences, University of Kasdi Merbah Ouargla, PO Box 511, 30000 Ouargla, Algeria | ||
| 2Laboratory of Water Engineering and Environment within the Saharian milieu, Department of Agricultural Sciences, Faculty of Natural Sciences and Life, University of Kasdi Merbah Ouargla, PO Box 511, 30000 Ouargla, Algeria | ||
| چکیده | ||
| This paper aims to study the possibility of providing a low-cost alternative for the adsorbents used in the fluoride adsorption from water by using eggshells. Indeed, eggshells were used as an adsorbent for fluoride adsorption from a drinking groundwater sample containing (2.14 mg/l) of fluoride. The eggshells were crushed and sieved into three particle sizes (0.2, 0.5, and 1mm) and then heated at different temperatures ranging from 100 to 250°C. XRD, FT-IR, pHpzc, and TG/DTA analysis were used for the characterization of the adsorbents. Adsorption batch experiments were carried out to determine the adsorption capacity of eggshell powder such as, particle size, preparation temperature, contact time, and adsorbent dose. A spectrophotometer UV-VIS was used to assess fluoride removal efficiency. The eggshell powder heated at 250°C with 0.2mm of particle size was found to be the most efficient adsorbent, with a maximum fluoride removal efficiency of 51.4%, a maximum adsorption capacity of 0.052mg/g, and a residual fluoride concentration of 1.1mg/l within 150 minutes. The data of the adsorption kinetic on ES250°0.2 were successfully fitted with the pseudo-second-order model with a satisfying coefficient of determination (R2=0.993). The results of the intra-particle diffusion model showed a multi-linearity, revealing that the diffusion of fluoride into the adsorbent was by two stages with diffusion rate constants of Ki = 0.007 (mg /g/min1/2) and Ki = 0.001(mg /g/min1/2) for the first and second stage respectively. An adsorbent dose of 1.5g and 1 hour of contact time were sufficient to decrease fluoride concentration from 2.14 to 1.1mg/l. | ||
| کلیدواژهها | ||
| Adsorption؛ Bio-sorbent؛ Fluoride؛ Kinetics | ||
| مراجع | ||
|
Aissa, R.B. and Boutoutaou, D. (2017). Characterization of groundwater in arid zones (case of Ouargla basin). Energy Procedia, International Conference on Technologies and Materials for Renewable Energy. Environment and Sustainability, TMREES17, 21-24 April 2017, Beirut Lebanon 119, 556–564. https://doi.org/10.1016/j.egypro.2017.07.077 Ait Taleb, M., Rachid, M., Benomar, M., Bakka, A., Mouna, A., Taha, M., Abdeljalil, B., Bakiz, B. and Villain, S. (2017). Chemically treated eggshell wastes as a heterogeneous and eco-friendly catalyst for oximes preparation. Journal of Environmental Chemical Engineering, 5. https://doi.org/10.1016/j.jece.2017.02.009 Aliaskari, M. and Schäfer, A. I. (2021). Nitrate, arsenic and fluoride removal by electrodialysis from brackish groundwater. Water Research, 190, 116683. https://doi.org/10.1016/j.watres.2020.116683 Annan, E., Nyankson, E., Agyei-Tuffour, B., Armah, S. K., Nkrumah-Buandoh, G., Hodasi, J. A. M. and Oteng-Peprah, M. (2021). Synthesis and Characterization of Modified Kaolin-Bentonite Composites for Enhanced Fluoride Removal from Drinking Water. Advances in Materials Science and Engineering, 2021, e6679422. https://doi.org/10.1155/2021/6679422 Bhaumik, R., Mondal, N. K., Das, B., Roy, P., Pal, K. C., Das, C., Baneerjee, A. and Datta, J. kumar. (2012). Eggshell Powder as an Adsorbent for Removal of Fluoride from Aqueous Solution: Equilibrium, Kinetic and Thermodynamic Studies. E-Journal of Chemistry, 9(3), 1457–1480. https://doi.org/10.1155/2012/790401 Bouziane, M. T. and Abdallah Seddik, L. (2009). Les Eaux Profondes de la Région de Biskra (Algérie). European Journal of Scientific Research, 25 (4), 526-537. Castro, L. da S., Barañano, A. G., Pinheiro, C. J. G., Menini, L. and Pinheiro, P. F. (2019). Biodiesel production from cotton oil using heterogeneous CaO catalysts from eggshells prepared at different calcination temperatures. Green Processing and Synthesis, 8(1), 235–244. https://doi.org/10.1515/gps-2018-0076 Chatterjee, S., Mukherjee, M. and De, S. (2018). Defluoridation using novel chemically treated carbonized bone meal: Batch and dynamic performance with scale-up studies. Environmental Science and Pollution Research, 25(18), 18161–18178. https://doi.org/10.1007/s11356-018-2025-z Choudhary, R., Koppala, S. and Swamiappan, S. (2015). Bioactivity studies of calcium magnesium silicate prepared from eggshell waste by sol–gel combustion synthesis. Journal of Asian Ceramic Societies, 3(2), 173–177. https://doi.org/10.1016/j.jascer.2015.01.002 Chouhan, S. and Flora, S. J. S. (2010). Arsenic and fluoride: Two major ground water pollutants. Indian Journal of Experimental Biology, 48(7), 666–678. Engin, B., Demirtaş, H. and Eken, M. (2006). Temperature effects on egg shells investigated by XRD, IR and ESR techniques. Radiation Physics and Chemistry, 75(2), 268–277. https://doi.org/10.1016/j.radphyschem.2005.09.013 Fan, S., Yuan, X., Zhao, L., Xu, L.-H., Kang, T.-J. and Kim, H.-T. (2016). Experimental and kinetic study of catalytic steam gasification of low rank coal with an environmentally friendly, inexpensive composite K2CO3–eggshell derived CaO catalyst. Fuel, 165, 397–404. https://doi.org/10.1016/j.fuel.2015.10.084 Goli, J. and Sahu, O. (2018). Development of heterogeneous alkali catalyst from waste chicken eggshell for biodiesel production. Renewable Energy, 128, 142–154. https://doi.org/10.1016/j.renene.2018.05.048 Hamidi, A. A., Salimi, M. N. and Yusoff, A. H. M. (2017). Synthesis and characterization of eggshell-derived hydroxyapatite via mechanochemical method: A comparative study. AIP Conference Proceedings, 1835(1), 020045. https://doi.org/10.1063/1.4981867 He, Z., Lan, H., Gong, W., Liu, R., Gao, Y., Liu, H. and Qu, J. (2016). Coagulation behaviors of aluminum salts towards fluoride: Significance of aluminum speciation and transformation. Separation and Purification Technology, 165, 137–144. https://doi.org/10.1016/j.seppur.2016.01.017 Ho, Y. S. and McKay, G. (1998). Sorption of dye from aqueous solution by peat. Chemical Engineering Journal, 70(2), 115–124. https://doi.org/10.1016/S0923-0467(98)00076-1 Ho, Y. S. and McKay, G. (1999). The sorption of lead(II) ions on peat. Water Research, 33(2), 578–584. https://doi.org/10.1016/S0043-1354(98)00207-3 Kaseva, M. E. (2006). Optimization of regenerated bone char for fluoride removal in drinking water: A case study in Tanzania. Journal of Water and Health, 4(1), 139–147. https://doi.org/10.2166/wh.2006.0011 Khatibi, M., Khorasheh, F. and Larimi, A. (2021). Biodiesel production via transesterification of canola oil in the presence of Na–K doped CaO derived from calcined eggshell. Renewable Energy, 163, 1626–1636. https://doi.org/10.1016/j.renene.2020.10.039 Lagergren, S. (1898). About the Theory of So-Called Adsorption of Soluble Substances. In Kungliga Svenska Vetenskapsakademiens Handlingar (Vol. 24, pp. 1–39). Lalley, J., Han, C., Li, X., Dionysiou, D. D. and Nadagouda, M. N. (2016). Phosphate adsorption using modified iron oxide-based sorbents in lake water: Kinetics, equilibrium, and column tests. Chemical Engineering Journal, 284, 1386–1396. https://doi.org/10.1016/j.cej.2015.08.114 Lee, J.-I., Hong, S.-H., Lee, C.-G. and Park, S.-J. (2021). Fluoride removal by thermally treated egg shells with high adsorption capacity, low cost, and easy acquisition. Environmental Science and Pollution Research, 28(27), 35887–35901. https://doi.org/10.1007/s11356-021-13284-z Lunge, S., Thakre, D., Kamble, S., Labhsetwar, N. and Rayalu, S. (2012). Alumina supported carbon composite material with exceptionally high defluoridation property from eggshell waste. Journal of Hazardous Materials, 237–238, 161–169. https://doi.org/10.1016/j.jhazmat.2012.08.023 Medellin-Castillo, N. A., Leyva-Ramos, R., Ocampo-Perez, R., Garcia de la Cruz, R. F., Aragon-Piña, A., Martinez-Rosales, J. M., Guerrero-Coronado, R. M. and Fuentes-Rubio, L. (2007). Adsorption of Fluoride from Water Solution on Bone Char. Industrial and Engineering Chemistry Research, 46(26), 9205–9212. https://doi.org/10.1021/ie070023n Mourabet, M., El Rhilassi, A., El Boujaady, H., Bennani-Ziatni, M., El Hamri, R. and Taitai, A. (2015). Removal of fluoride from aqueous solution by adsorption on hydroxyapatite (HAp) using response surface methodology. Journal of Saudi Chemical Society, 19(6), 603–615. https://doi.org/10.1016/j.jscs.2012.03.003 Murakami, F. S., Rodrigues, P. O., Campos, C. M. T. de, and Silva, M. A. S. (2007). Physicochemical study of CaCO3 from egg shells. Food Science and Technology, 27, 658–662. https://doi.org/10.1590/S0101-20612007000300035 Mutchimadilok, Y., Smittakorn, S., Mongkolnchai-arunya, S. and Durnford, D. (2014). Defluoridation with Locally Produced Thai Bone Char. Advances in Environmental Chemistry, 2014, e483609. https://doi.org/10.1155/2014/483609 Nigri, E. M., Cechinel, M. Alice. P., Mayer, D. A., Mazur, Luciana. P., Loureiro, J. M., Rocha, S. D. F. and Vilar, V. J. P. (2017). Cow bones char as a green sorbent for fluorides removal from aqueous solutions: Batch and fixed-bed studies. Environmental Science and Pollution Research, 24(3), 2364–2380. https://doi.org/10.1007/s11356-016-7816-5 Ooi, C. Y., Hamdi, M. and Ramesh, S. (2007). Properties of hydroxyapatite produced by annealing of bovine bone. Ceramics International, 33(7), 1171–1177. https://doi.org/10.1016/j.ceramint.2006.04.001 Owusu-Agyeman, I., Reinwald, M., Jeihanipour, A. and Schäfer, A. I. (2019). Removal of fluoride and natural organic matter from natural tropical brackish waters by nanofiltration/reverse osmosis with varying water chemistry. Chemosphere, 217, 47–58. https://doi.org/10.1016/j.chemosphere.2018.10.135 Pereira, A. P., Silva, M., Jr, É., Paula, A. and Tommasini, F. (2017). Processing and Characterization of PET Composites Reinforced With Geopolymer Concrete Waste. Materials Research. https://doi.org/10.1590/1980-5373-mr-2017-0734 Pérez, S., Muñoz-Saldaña, J., Acelas, N. and Flórez, E. (2021). Phosphate removal from aqueous solutions by heat treatment of eggshell and palm fiber. Journal of Environmental Chemical Engineering, 9(1), 104684. https://doi.org/10.1016/j.jece.2020.104684 Rodier, J. (2009). L’Analyse de l’Eau: Eaux Naturelles, Eaux Résiduaires, Eau de Mer (9e édn, pp. 100-110). Paris: Dunod. Saini, A., Maheshwari, P. H., Tripathy, S. S., Waseem, S., Gupta, A. and Dhakate, S. R. (2021). A novel alum impregnated CaO/ carbon composite for de-fluoridation of water. Groundwater for Sustainable Development, 14, 100622. https://doi.org/10.1016/j.gsd.2021.100622 Samrat, M. V. V. N., Gandhi, K. S. and Rao, K. K. (2020). Modelling the adsorption of fluoride onto activated alumina in the presence of other ions. Journal of Environmental Chemical Engineering, 8(5), 103934. https://doi.org/10.1016/j.jece.2020.103934 Shahid, M. K., Kim, J. Y., Shin, G. and Choi, Y. (2020). Effect of pyrolysis conditions on characteristics and fluoride adsorptive performance of bone char derived from bone residue. Journal of Water Process Engineering, 37, 101499. https://doi.org/10.1016/j.jwpe.2020.101499 Shen, J., Richards, B. S. and Schäfer, A. I. (2016). Renewable energy powered membrane technology: Case study of St. Dorcas borehole in Tanzania demonstrating fluoride removal via nanofiltration/reverse osmosis. Separation and Purification Technology, 170, 445–452. https://doi.org/10.1016/j.seppur.2016.06.042 Spelta, J. and Galdino, A. (2018). BIOCERAMIC COMPOSITE: HEN’S EGGSHELL CHARACTERIZATION AND MAIN APPLICATIONS. Revista Ifes Ciência, 4, 12. https://doi.org/10.36524/ric.v4i1.323 Srimurali, M., Pragathi, A. and Karthikeyan, J. (1998). A study on removal of fluorides from drinking water by adsorption onto low-cost materials. Environmental Pollution, 99(2), 285–289. https://doi.org/10.1016/S0269-7491(97)00129-2 Sternitzke, V., Kaegi, R., Audinot, J.-N., Lewin, E., Hering, J. G. and Johnson, C. A. (2012). Uptake of fluoride from aqueous solution on nano-sized hydroxyapatite: Examination of a fluoridated surface layer. Environmental Science and Technology, 802–809. https://doi.org/10.1021/es202750t Tangboriboon, N., Kunanuruksapong, R. and Sirivat, A. (2012). Preparation and properties of calcium oxide from eggshells via calcination. Materials Science-Poland, 30(4), 313–322. https://doi.org/10.2478/s13536-012-0055-7 Tizo, M. S., Blanco, L. A. V., Cagas, A. C. Q., Dela Cruz, B. R. B., Encoy, J. C., Gunting, J. V., Arazo, R. O. and Mabayo, V. I. F. (2018). Efficiency of calcium carbonate from eggshells as an adsorbent for cadmium removal in aqueous solution. Sustainable Environment Research, 28(6), 326–332. https://doi.org/10.1016/j.serj.2018.09.002 Torres-Mansilla, A. and Delgado-Me, E. (2017). Influence of Separation Techniques with Acid Solutions on the Composition of Eggshell Membrane. International Journal of Poultry Science, 16, 451–456. https://doi.org/10.3923/ijps.2017.451.456 Viswanathan, N., Prabhu, S. M. and Meenakshi, S. (2013). Development of amine functionalized co-polymeric resins for selective fluoride sorption. Journal of Fluorine Chemistry, 153, 143–150. https://doi.org/10.1016/j.jfluchem.2013.04.002 Weber, W. J. and Morris, J. C. (1963). Kinetics of Adsorption on Carbon from Solution. Journal of the Sanitary Engineering Division, 89(2), 31–59. https://doi.org/10.1061/JSEDAI.0000430 Whitford, G. M. (1996). The metabolism and toxicity of fluoride. Monographs in Oral Science, 16 Rev 2, 1–153. World Health Organization. (2022). Guidelines for drinking‑water quality: Fourth edition incorporating the first and second addenda (4th ed + 1st add + 2nd add). World Health Organization. https://apps.who.int/iris/handle/10665/352532 Xia, Y., Huang, X., Li, W., Zhang, Y. and Li, Z. (2019). Facile defluoridation of drinking water by forming shell@fluorapatite nanoarray during boiling egg shell. Journal of Hazardous Materials, 361, 321–328. https://doi.org/10.1016/j.jhazmat.2018.09.007 | ||
|
آمار تعداد مشاهده مقاله: 573 تعداد دریافت فایل اصل مقاله: 894 |
||