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Application of Surfactant Modified Kono-Boue Clay Nanoparticles in Oil Recovery | ||
| Journal of Chemical and Petroleum Engineering | ||
| دوره 59، شماره 1، شهریور 2025، صفحه 173-184 اصل مقاله (587.29 K) | ||
| نوع مقاله: Research Paper | ||
| شناسه دیجیتال (DOI): 10.22059/jchpe.2024.383870.1566 | ||
| نویسندگان | ||
| Ogochukwu Vivian Udeh1؛ JOSHUA LELESI KONNE* 2؛ Grace Agbizu Cookey3؛ Godwin Chukwuma Jacob Nmegbu4 | ||
| 1Rivers State University, Rivers State, Nigeria. | ||
| 2Faculty of Science, Nigeria. | ||
| 3Faculty of Science, Nkpolu-Oroworukwo, Nigeria. | ||
| 4Department of Petroleum Engineering, Rivers State University, Port Harcourt, Nigeria. | ||
| چکیده | ||
| Sodium Dodecyl Sulphate (SDSodium Dodecyl Sulphate (SDS) mediated Kono-Bono (KB) clay nanoparticles (NPs) applied in Enhanced Oil Recovery (EOR) have been investigated for the first time. This was done using synthesized KB clay NPs as a control and SDS-treated KB clay NPs experiments in a micro model to determine the oil recovery rate. The samples were prepared by dissolving 15 g of KB clay in a mixture of 450 ml of de-ionized water and 150 ml of varying SDS concentrations, magnetically stirred, dried at 110 °C for 90 minutes, and further calcined at 900 °C in a muffle furnace for 120 minutes. The samples were characterized with Fourier Transform infrared (FT-IR) Spectroscopy, Scanning Electron Microscopy (SEM), X-ray fluorescence (XRF), and X-ray Diffraction (XRD), respectively. FT-IR analysis indicated characteristic bending vibrations of Al-OH bands at 698 cm-1 and stretching modes at 780, 1056, and 3655 cm-1 for (Si-O and Al-Mg-OH) bands, respectively. SEM micrographs showed surfaces with varying platy polycrystalline particle sizes, while XRF results identified the clay as kaolinite with silicate and alumina > 30 and 16%, respectively. The flooding experiment revealed that the SDS-mediated KB clay NPs (8.33 mM SDS) gave the highest total oil recovery of 66.25 % at 0.10 wt. %. Optimizing oil recovery at 8.33 mM by varying concentrations of KBC2 at 0.05, 0.10, 0.15, 0.20, and 0.25 wt. % gave a remarkable oil recovery rate of 85.27% at 0.15 wt.%. Thus, 0.15 wt. % KBC2 is recommended for application in oil recovery.S) mediated Kono-Bono (KB) clay nanoparticles (NPs) applied in Enhanced Oil Recovery (EOR) have been investigated for the first time. This was done using synthesized KB clay NPs as a control and SDS-treated KB clay NPs experiments in a micro model to determine the oil recovery rate. The samples were prepared by dissolving 15 g of KB clay in a mixture of 450 ml of de-ionized water and 150 ml of varying SDS concentrations, magnetically stirred, dried at 110 °C for 90 minutes, and further calcined at 900 °C in a muffle furnace for 120 minutes. The samples were characterized with Fourier Transform infrared (FT-IR) Spectroscopy, Scanning Electron Microscopy (SEM), X-ray fluorescence (XRF), and X-ray Diffraction (XRD), respectively. FT-IR analysis indicated characteristic bending vibrations of Al-OH bands at 698 cm-1 and stretching modes at 780, 1056, and 3655 cm-1 for (Si-O and Al-Mg-OH) bands, respectively. SEM micrographs showed surfaces with varying platy polycrystalline particle sizes, while XRF results identified the clay as kaolinite with silicate and alumina > 30 and 16%, respectively. The flooding experiment revealed that the SDS-mediated KB clay NPs (8.33 mM SDS) gave the highest total oil recovery of 66.25 % at 0.10 wt. %. Optimizing oil recovery at 8.33 mM by varying concentrations of KBC2 at 0.05, 0.10, 0.15, 0.20, and 0.25 wt. % gave a remarkable oil recovery rate of 85.27% at 0.15 wt.%. Thus, 0.15 wt. % KBC2 is recommended for application in oil recovery. | ||
| کلیدواژهها | ||
| Enhanced Oil Recovery؛ Kono-Boue Clay؛ Micro Model؛ Nanoparticles؛ SDS- Mediated | ||
| مراجع | ||
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