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برهمکنش اجزای مختلف کربن آلی با شکلهای مختلف آهن و آلومینیوم در خاکهای دارای خواص اندیک تیمار شده با اسید هیومیک | ||
تحقیقات آب و خاک ایران | ||
دوره 56، شماره 4، تیر 1404، صفحه 899-917 اصل مقاله (1.52 M) | ||
نوع مقاله: مقاله پژوهشی | ||
شناسه دیجیتال (DOI): 10.22059/ijswr.2025.385625.669840 | ||
نویسندگان | ||
محمد علی منجم1؛ احمد حیدری* 2 | ||
1گروه علوم و مهندسی خاک، دانشکده کشاورزی، دانشگا تهران، کرج، ایران | ||
2گروه علوم و مهندسی خاک، دانشکده کشاورزی، دانشگاه تهران، کرج، ایران | ||
چکیده | ||
کمپلکسهای آلی-معدنی که عمدتا حاصل برهمکنش اجزای کربن آلی با مواد معدنی خاک هستند، از مهمترین عوامل تاثیرگذار بر چرخه کربن و کارکردهای خاک میباشند. هدف این مطالعه بررسی نقش کانیهای آلوفانی و اشکال مختلف آهن و آلومینیم خاک، در تثبیت کربن آلی ورودی میباشد. اجزای کربن آلی و اشکال مختلف آهن و آلومینیوم قبل و بعد از تیمار دوازده نمونه خاک دارای خواص اندیک با اسید هیومیک به مدت شش ماه در شرایط آزمایشگاهی، اندازهگیری شدند. نتایج نشان نشان داد، تثبیت کربن آلی، با تشکیل کمپلکسهای آلی- معدنی، عمدتا توسط کانیهای با آرایشدامنهکوتاه (آلوفان) کنترل میشود. تشکیل کمپلکسهای سطحی بین عوامل پیوندی واقع در سطوح مواد معدنی و موادآلی، یکی از مهمترین فرایندهای تثبیت موادآلی در خاک است. کمپلکسهای آلومینیم و/یا آهن–هوموس دیگر عامل مهم در تثبیت موادآلی خاک میباشند. تثبیت و تشکیل کمپلکس با موادآلی، کانیهای با درجه تبلور پایین، آهن آمورف (Feo)، نبست به Alo آمورف مهمترین نقش را در تثبیت مواد آلی دارند. مقایسه میانگین (05/0p<) مقادیر اشکال سیلیس و آهن اگزالاتی (Feo، Sio)؛ پیروفسفاتی (Alp، Fep) و کل Fet حاکی از اختلاف معنیدار بین نمونههای تیمار و شاهد بود. افزودن اسید هیومیک با تشکیل کمپلکسهای آلی نامحلول با سطوح کانیها از یک طرف، و آلومینیم و آهنِ آزاد شده در خاک از طرف دیگر موجب تثبیت بیشتر کربن آلی در خاک شده است. تشکیل پلهای کاتیونی بین بار الکتریکی گروههای عاملی اسیدهیومیک با آلوفانها و تشکیل کمپلکسهای آلی- فلزی پایدار مانع استخراج آهن و آلومینیوم توسط اگزالات آمونیوم و یا پیروفسفات سدیم شد. | ||
کلیدواژهها | ||
کمپلکس آلی_ معدنی؛ هیومیک اسید؛ عناصر قابل استخراج (آلومینیم و آهن)؛ سدیم هیپوکلریت؛ اسید هیدروفلوئوریک | ||
عنوان مقاله [English] | ||
The interaction of different components of organic carbon with varying forms of iron and aluminum in soils with andic properties treated with humic acid | ||
نویسندگان [English] | ||
Mohammad Ali Monajjem1؛ Ahmad Heidari2 | ||
1Soil Science Department, Faculty of Agriculture, University of Tehran, Karaj, ran | ||
2Soil Science Departmen, Faculty of Agriculture, University of Tehran, Karaj, Iran | ||
چکیده [English] | ||
Organic-mineral complexes, which are mainly the result of the interaction of organic and mineral soil materials, are one of the most important factors influencing the carbon cycle and soil functions. This study aims to investigate the role of allophanic minerals, and different forms of soil iron and aluminum in stabilizing input organic carbon. Organic carbon components and different forms of iron and aluminum were measured before and after treating the twelve soil samples with andic properties, with humic acid for six months under laboratory conditions. The results showed that the stabilization of organic carbon is mainly controlled by the formation of organic-mineral complexes, and the allophanes. The formation of surface complexes between bonding agents on the surfaces of mineral and organic materials is one of the most important processes of organic material stabilization in soil. Aluminum and/or iron-humus complexes are another important factor in stabilizing soil organic matter. Stabilization and complex formation with organic materials, allophanes, amorphous iron and aluminium (Feo, Alo), play the most important role in stabilizing organic materials. Comparison of oxalate extractable silica and iron (Feo, Sio); Pyrophosphate extractable (Alp, Fep), and total iron (Fet) (p<0.05) indicated a significant difference between the treated and control samples. The addition of humic acid, by forming insoluble organic complexes with mineral surfaces on the one hand, and with aluminum and iron released in the soil on the other hand, has caused more stabilization of organic carbon in the soil. The formation of cationic bridges between the electric charge of humic acid functional groups, with allophanes, and the formation of stable organic-metallic complexes has prevented the extraction of iron and aluminum by ammonium oxalate or sodium pyrophosphate. | ||
کلیدواژهها [English] | ||
Organo-mineral complexes, Humic Acid, Extractable Al and Fe, NaOCl, HF | ||
مراجع | ||
Anda, M., & Dahlgren, R. A. (2020). Long-term response of tropical Andisol properties to conver on from rainforest to agriculture. Catena, (194), 104679. Asano, M., & Wagai, R. (2014). Evidence of aggregate hierarchy at micro-to submicron scales in an allophanic Andisol. Geoderma, (216), 62-74. Auxtero, E., Madeira, M., & Sousa, E. (2004). Variable charge characteristics of selected Andisols from the Azores, Portugal. Catena, 56(1-3), 111-125. Baldock, J. A. (2007). Composition and cycling of organic carbon in soil. In Nutrient cycling in terrestrial ecosystems (pp. 1-35). Berlin, Heidelberg: Springer Berlin Heidelberg. Bascomb, C. L. (1968). Distribution of pyrophosphate‐extractable iron and organic carbon in soils of various groups. Journal of Soil Science, 19(2), 251-268. Basile-Doelsch, I., Amundson, R., Stone, W. E. E., Borschneck, D., Bottero, J. Y., Moustier, S., ... & Colin, F. (2007). Mineral control of carbon pools in a volcanic soil horizon. Geoderma, 137(3-4), 477-489. Basile‐Doelsch, I., Amundson, R., Stone, W. E. E., Masiello, C. A., Bottero, J. Y., Colin, F., ... & Meunier, J. D. (2005). Mineralogical control of organic carbon dynamics in a volcanic ash soil on La Réunion. European Journal of Soil Science, 56(6), 689-703. Blakemore, L. C., Searle, P. L., & Daly, B. K. (1987). Methods for chemical analysis of soils. Bonifacio, E., Catoni, M., Falsone, G., Said-Pullicino, D., & Celi, L. (2013). Evolution of surface properties and organic matter stabilisation in podzolic B horizons as assessed by nitrogen and phosphate sorption. Biology and fertility of soils, (49), 505-516. Calabi-Floody, M., Bendall, J. S., Jara, A. A., Welland, M. E., Theng, B. K., Rumpel, C., & de La Luz Mora, M. (2011). Nanoclays from an Andisol: extraction, properties and carbon stabilization. Geoderma, 161(3-4), 159-167. Calabi-Floody, M., Rumpel, C., Velásquez, G., Violante, A., Bol, R., Condron, L. M., & Mora, M. L. (2015). Role of Nanoclays in Carbon stabilization in Andisols and Cambisols. Journal of soil science and plant nutrition, 15(3), 587-604. Catoni, M., D'Amico, M. E., Zanini, E., & Bonifacio, E. (2016). Effect of pedogenic processes and formation factors on organic matter stabilization in alpine forest soils. Geoderma, (263), 151-160. Chen, C., Kukkadapu, R. K., Lazareva, O., & Sparks, D. L. (2017). Solid-phase Fe speciation along the vertical redox gradients in floodplains using XAS and Mossbauer spectroscopies. Environmental science & technology, 51(14), 7903-7912. Chen, S., Hong, H., Huang, X., Fang, Q., Yin, K., Wang, C., ... & Algeo, T. J. (2018). The role of organo-clay associations in limiting organic matter decay: Insights from the Dajiuhu peat soil, central China. Geoderma, (320), 149-160. Chevallier, T., Fujisaki, K., Roupsard, O., Guidat, F., Kinoshita, R., de Melo Viginio Filho, E., ... & Albrecht, A. (2019). Short-range-order minerals as powerful factors explaining deep soil organic carbon stock distribution: the case of a coffee agroforestry plantation on Andosols in Costa Rica. Soil, 5(2), 315-332. Churchman, G. J., & Lowe, D. J. (2012). Alteration, formation, and occurrence of minerals in soils (pp. 1-72). CRC press. Debnath, S., Attri, B. L., Kumar, A., Kishor, A., Narayan, R., Sinha, K., ... & Singh, D. B. (2020). Influence of peach (Prunus persica Batsch) phenological stage on the short-term changes in oxidizable and labile pools of soil organic carbon and activities of carbon-cycle enzymes in the North-Western Himalayas. Pedosphere, 30(5), 638-650. Feng, W., Plante, A. F., Aufdenkampe, A. K., & Six, J. (2014). Soil organic matter stability in organo-mineral complexes as a function of increasing C loading. Soil Biology and Biochemistry, 69, 398-405. Fiantis, D., Ginting, F. I., Nelson, M., & Minasny, B. (2019). Volcanic ash, Insecurity for the people but securing fertile soil for the future. Sustainability, 11(11), 3072. Garcıa-Rodeja, E., Nóvoa, J. C., Pontevedra, X., Martınez-Cortizas, A., & Buurman, P. (2004). Aluminium fractionation of European volcanic soils by selective dissolution techniques. Catena, 56(1-3), 155-183. Garrido, E., & Matus, F. (2012). Are organo-mineral complexes and allophane content determinant factors for the carbon level in Chilean volcanic soils?. Catena, (92), 106-112. Giannetta, B., Plaza, C., Vischetti, C., Cotrufo, M. F., & Zaccone, C. (2018). Distribution and thermal stability of physically and chemically protected organic matter fractions in soils across different ecosystems. Biology and Fertility of Soils, (54), 671-681. Håkansson, I., & Lipiec, J. (2000). A review of the usefulness of relative bulk density values in studies of soil structure and compaction. Soil and Tillage Research, 53(2), 71-85. Hashizume, H., & Theng, B. K. (2007). Adenine, adenosine, ribose and 5′-AMP adsorption to allophane. Clays and Clay Minerals, (55), 599-605. Jansen, B., Tonneijck, F. H., & Verstraten, J. M. (2011). Selective extraction methods for aluminium, iron and organic carbon from montane volcanic ash soils. Pedosphere, 21(5), 549-565. Kleber, M. (2010). What is recalcitrant soil organic matter?. Environmental Chemistry, 7(4), 320-332. Kleber, M., Eusterhues, K., Keiluweit, M., Mikutta, C., Mikutta, R., & Nico, P. S. (2015). Mineral–organic associations: formation, properties, and relevance in soil environments. Advances in agronomy, (130), 1-140. Kleber, M., Mikutta, R., Torn, M. S., & Jahn, R. (2005). Poorly crystalline mineral phases protect organic matter in acid subsoil horizons. European Journal of Soil Science, 56(6), 717-725. Kögel-Knabner, I. (2002). The macromolecular organic composition of plant and microbial residues as inputs to soil organic matter. Soil biology and biochemistry, 34(2), 139-162. Lal, R. (2018). Digging deeper: A holistic perspective of factors affecting soil organic carbon sequestration in agroecosystems. Global change biology, 24(8), 3285-3301. Levard, C., Doelsch, E., Basile-Doelsch, I., Abidin, Z., Miche, H., Masion, A., ... & Bottero, J. Y. (2012). Structure and distribution of allophanes, imogolite and proto-imogolite in volcanic soils. Geoderma, (183), 100-108. Lilienfein, J., Qualls, R. G., Uselman, S. M., & Bridgham, S. D. (2003). Soil formation and organic matter accretion in a young andesitic chronosequence at Mt. Shasta, California. Geoderma, 116(3-4), 249-264. Lützow, M. V., Kögel‐Knabner, I., Ekschmitt, K., Matzner, E., Guggenberger, G., Marschner, B., & Flessa, H. (2006). Stabilization of organic matter in temperate soils: mechanisms and their relevance under different soil conditions–a review. European journal of soil science, 57(4), 426-445. Matus, F., Garrido, E., Sepúlveda, N., Cárcamo, I., Panichini, M., & Zagal, E. (2008). Relationship between extractable Al and organic C in volcanic soils of Chile. Geoderma, 148(2), 180-188. McDaniel, P. A., Lowe, D. J., Arnalds, O., & Ping, C. L. (2012). Andisols. Mikutta, R., Kleber, M., Torn, M. S., & Jahn, R. (2006). Stabilization of soil organic matter: association with minerals or chemical recalcitrance?. Biogeochemistry, (77), 25-56. Mizota, C., & Reeuwijk, L. V. (1989). Clay mineralogy and chemistry of soils formed in volcanic material in diverse climatic regions. Möckel, S. C., Erlendsson, E., & Gísladóttir, G. (2021). Andic soil properties and tephra layers hamper C turnover in Icelandic peatlands. Journal of Geophysical Research: Biogeosciences, 126(12), e2021JG006433. Molina, E., Bornemisza, E., Sancho, F., & Kass, D. L. (1991). Soil aluminum and iron fractions and their relationships with P immobilization and other soil properties in andisols of Costa Rica and Panama. Communications in soil science and plant analysis, 22(13-14), 1459-1476. Monajjem, M. A. (2013). An investigation the role of nanoclays on some soil physico-chemical properties, MSc.Thesis, Supervisors: Heidari, A., Bagheri Marandi, G. Iran, Tehran. College of Agriculture and Natural Resources (In Persian). Monajjem, M. A. (2025). Organo-mineral complexes and their role on the fixation of organic carbon in volcanic soils, Thesis Ph.D, Supervisors: Heidari, A., Bonifacio, E. Iran, Tehran. College of Agriculture and Natural Resources (In Persian). Monajjem, M. A., Bonifacio, E., & Heidari, A., (2025). Organic matter fractions and stabilization potential in some Andosols of Iran. Geoderma Regional, Volume 40, e00923. https://doi.org/10.1016/j.geodrs.2025.e00923 Nanzyo, M. (2002). Unique properties of volcanic ash soils. Global Environmental Research-English Edition-, 6(2), 99-112. Panichini, M., Neculman, R., Godoy, R., Arancibia-Miranda, N., & Matus, F. (2017). Understanding carbon storage in volcanic soils under selectively logged temperate rainforests. Geoderma, (302), 76-88. Parfitt, R. L., & Hemni, T. (1980). Structure of some allophanes from New Zealand. Clays and Clay Minerals, (28), 285-294. Paul, E. A. (2016). The nature and dynamics of soil organic matter: Plant inputs, microbial transformations, and organic matter stabilization. Soil Biology and Biochemistry, (98), 109-126. Percival, H. J., Parfitt, R. L., & Scott, N. A. (2000). Factors controlling soil carbon levels in New Zealand grasslands is clay content important?. Soil Science Society of America Journal, 64(5), 1623-1630. Pereira, R. C., Arbestain, M. C., Kelliher, F. M., Theng, B. K. G., McNally, S. R., Macías, F., & Guitián, F. (2019). Assessing the pore structure and surface area of allophane-rich and non-allophanic topsoils by supercritical drying and chemical treatment. Geoderma, (337), 805-811. Poblete-Grant, P., Suazo-Hernández, J., Condron, L., Rumpel, C., Demanet, R., Malone, S. L., & Mora, M. D. L. L. (2020). Soil available P, soil organic carbon and aggregation as affected by long-term poultry manure application to Andisols under pastures in Southern Chile. Geoderma Regional, (21), e00271. Porras, R. C., Hicks Pries, C. E., McFarlane, K. J., Hanson, P. J., & Torn, M. S. (2017). Association with pedogenic iron and aluminum: effects on soil organic carbon storage and stability in four temperate forest soils. Biogeochemistry, (133), 333-345. Quan, G., Fan, Q., Sun, J., Cui, L., Wang, H., Gao, B., & Yan, J. (2020). Characteristics of organo-mineral complexes in contaminated soils with long-term biochar application. Journal of hazardous materials, (384), 121265. Rasmussen, C., Southard, R. J., & Horwath, W. R. (2006). Mineral control of organic carbon mineralization in a range of temperate conifer forest soils. Global Change Biology, 12(5), 834-847. Richards, B. K., Steenhuis, T. S., Peverly, J. H., & McBride, M. B. (1998). Metal mobility at an old, heavily loaded sludge application site. Environmental pollution, 99(3), 365-377. Schmidt, M. W. I., & Gleixner, G. (2005). Carbon and nitrogen isotope composition of bulk soils, particle‐size fractions and organic material after treatment with hydrofluoric acid. European Journal of Soil Science, 56(3), 407-416. Schmidt, M. W., Torn, M. S., Abiven, S., Dittmar, T., Guggenberger, G., Janssens, I. A., ... & Trumbore, S. E. (2011). Persistence of soil organic matter as an ecosystem property. Nature, 478(7367), 49-56. Schneider, M. P. W., Scheel, T., Mikutta, R., Van Hees, P., Kaiser, K., & Kalbitz, K. (2010). Sorptive stabilization of organic matter by amorphous Al hydroxide. Geochimica et Cosmochimica Acta, 74(5), 1606-1619. Shoji, S., Nanzyo, M., & Dahlgren, R. A. (1994). Volcanic ash soils: genesis, properties and utilization. Elsevier. Soil Survey Satff, N (2022) 'Keys to soil taxonomy by Soil Survey Staff', USDA Natural Resources Conservation Service. Sollins, P., Homann, P., & Caldwell, B. A. (1996). Stabilization and destabilization of soil organic matter: mechanisms and controls. Geoderma, 74(1-2), 65-105. Takahashi, T., & Dahlgren, R. A. (2016). Nature, properties and function of aluminum–humus complexes in volcanic soils. Geoderma, (263), 110-121. Takahashi, T., & Shoji, S. (2002). Distribution and classification of volcanic ash soils. Global Environmental Research-English Edition-, 6(2), 83-98. Takahashi, T., Kanno, H., & Nanzyo, M. (2012). Factors affecting organic carbon accumulation in humus horizons of volcanic soils from the Tohoku University World Andosol Database: a path analysis. Pedologist, 56(2), 58-62. Tonneijck, F. H., Jansen, B., Nierop, K. G. J., Verstraten, J. M., Sevink, J., & De Lange, L. (2010). Towards understanding of carbon stocks and stabilization in volcanic ash soils in natural Andean ecosystems of northern Ecuador. European Journal of Soil Science, 61(3), 392-405. Turrión, M. B., Gallardo, J. F., & González, M. I. (2002). Relationships between organic and inorganic P fractions with soil Fe and Al forms in forest soils of sierra de gata mountains (Western Spain). In Developments in Soil Science (Vol. 28, pp. 297-310). Elsevier. Van Ranst, E., Utami, S. R., & Shamshuddin, J. (2002). Andisols on volcanic ash from Java Island, Indonesia: Physico-chemical properties and classification. Soil Science, 167(1), 68-79. Van Ranst, E., Utami, S. R., Verdoodt, A., & Qafoku, N. P. (2008). Mineralogy of a perudic Andosol in central Java, Indonesia. Geoderma, 144(1-2), 379-386 Violante, A., Mora, M. D. L. L., & Caporale, A. G. (2017). Formation, properties and reactivity of coprecipitates and organomineral complexes in soil environments. Journal of soil science and plant nutrition, 17(2), 319-340. Wada, K. (1978). Allophane and imogolite. Developments in Sedimentology (Vol. 26, pp. 147-187). Elsevier. Wagai, R., & Mayer, L. M. (2007). Sorptive stabilization of organic matter in soils by hydrous iron oxides. Geochimica et Cosmochimica Acta, 71(1), 25-35. Wagai, R., Kajiura, M., Asano, M., & Hiradate, S. (2015). Nature of soil organo-mineral assemblage examined by sequential density fractionation with and without sonication: Is allophanic soil different?. Geoderma, (241), 295-305. Walkley. A, & Black C.A. (1934). An examination of the Dettjareff method for determining soil organic matter, and a proposed modification of the chromic acid titration method. Soil science. (37), 29-38. Wang, S., Du, P., Yuan, P., Zhong, X., Liu, Y., Liu, D., & Deng, L. (2018). Changes in the structure and porosity of hollow spherical allophane under alkaline conditions. Applied Clay Science, (166), 242-249. Wilson, S. G., Lambert, J. J., Nanzyo, M., & Dahlgren, R. A. (2017). Soil genesis and mineralogy across a volcanic lithosequence. Geoderma, (285), 301-312. Zhang, J. C., Zhang, L., Wang, P., Huang, Q. W., Yu, G. H., Li, D. C., ... & Ran, W. (2013). The role of non‐crystalline Fe in the increase of SOC after long‐term organic manure application to the red soil of s outhern C hina. European journal of soil science, 64(6), 797-804. | ||
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