| تعداد نشریات | 127 |
| تعداد شمارهها | 7,124 |
| تعداد مقالات | 76,627 |
| تعداد مشاهده مقاله | 153,529,169 |
| تعداد دریافت فایل اصل مقاله | 115,672,718 |
مقایسه کارایی بیوچار کاه وکلش برنج و هیدروکسید دوگانه لایهای منیزیم-آلومینیوم در حذف سرب از محلول آبی | ||
| تحقیقات آب و خاک ایران | ||
| دوره 57، شماره 1، فروردین 1405، صفحه 85-105 اصل مقاله (2.15 M) | ||
| نوع مقاله: مقاله پژوهشی | ||
| شناسه دیجیتال (DOI): 10.22059/ijswr.2026.404609.670043 | ||
| نویسندگان | ||
| فاطمه شکسته بند1؛ سید مصطفی عمادی* 2؛ محمدعلی بهمنیار1؛ اسماعیل گلی کلانپا3؛ مهدی قاجار سپانلو4 | ||
| 1گروه علوم و مهندسی خاک، دانشکده علوم زراعی، دانشگاه کشاورزی و منابع طبیعی ساری، ساری، ایران | ||
| 2هیات علمی/دانشگاه علوم کشاورزی و منابع طبیعی ساری | ||
| 3گروه علوم و مهندسی خاک، دانشکده کشاورزی و منابع طبیعی، دانشگاه محقق اردبیلی، اردبیل، ایران | ||
| 4گروه علوم و مهندسی خاک، دانشکده علوم زراعی، دانشگاه کشاورزی و منلع طبیعی ساری، ساری، ایران | ||
| چکیده | ||
| آلودگی سرب به منابع آب بهعنوان یک چالش زیستمحیطی، نیازمند توسعه روشهای بسیار کارآمد برای رفع آلودگی مانند استفاده از جاذبهای کارآمد، غیرسمی و کمهزینه است. این مطالعه با هدف مقایسه عملکرد بیوچار پوسته برنج (RHB) و هیدروکسیدهای دوگانه لایهای (Mg/Al-LDH) در حذف سرب از محلولهای آبی انجام شد. در این مطالعه، بیوچار از پیرولیز بقایای کاه و کلش برنج در دمای 500 درجه سلسیوس تحت شرایط محدود اکسیژن و هیدروکسیدهای دوگانه لایهای منیزیم/آلومینیوم با نسبت 2:1 به روش هم رسوبی تهیه شد. ارزیابی پارامترهایی شامل سینتیک جذب، ایزوترم و pH اولیه محلول بر جذب سرب انجام شد. طبق نتایج، مطالعات سینتیکی نشان داد که جذب سرب توسط RHB و LDH به ترتیب در 60 و 240 دقیقه به تعادل میرسد و مدل سینتیکی شبه درجه دوم توانایی بالایی در پیشبینی سینتیک جذب نشان داد. با افزایش pH اولیه محلول، جذب سرب توسط هر دو جاذب افزایش یافت. مدلهای لانگمویر توانایی بالایی در پیشبینی رفتار جذب سرب توسط جاذبها نشان دادند. حداکثر ظرفیت جذب سرب توسط RHB و LDH به ترتیب 83/297 و 46/173 میلیگرم بر گرم بود. مطالعات مکانیکی نشان داد که حذف سرب توسط بیوچار عمدتاً از طریق تبادل کاتیونی و تشکیل کمپلکسهای سطحی با گروههای عاملی حاوی اکسیژن رخ میدهد، در حالی که در LDH، فرآیند حذف به دلیل محدود بودن مکانهای فعال در منافذ ریز محدود است. نتایج این مطالعه تأیید میکند که بیوچار پوسته برنج میتواند به دلیل دسترسی بالای مکانهای فعال و عملکرد پایدار در طیف وسیعی از pH، به عنوان یک گزینه برتر، کمهزینه، غیرسمی و سازگار با محیط زیست برای رفع آلودگی سرب از محیطهای آبی در نظر گرفته شود. | ||
| کلیدواژهها | ||
| آلودگی؛ جاذب؛ سینتیک؛ ایزوترم؛ لانگمویر | ||
| عنوان مقاله [English] | ||
| Comparative Efficiency of Rice Husk Biochar and Magnesium/Aluminum Layered Double Hydroxide for Lead Removal from Aqueous Solution | ||
| نویسندگان [English] | ||
| Fatemeh Shekasteband1؛ Seyed Mostafa Emadi2؛ Mohammad Ali Bahmanyar1؛ Esmaiel Goli Kalanpa3؛ Mehdi Ghajar Sepanlou4 | ||
| 1Department of Soil Science and Engineering, Faculty of Crop Sciences, Sari Agricultural Sciences and Natural Resources University, Sari, Iran | ||
| 2Academic member/ Sari Agricultural Sciences and Natural Resources University, Sari, Iran | ||
| 3Department of Soil Science and Engineering, Faculty of Agriculture and Natural Resources, University of Mohaghegh Ardabili, Ardabil, Iran | ||
| 4Department of Soil Science and Engineering, Faculty of Crop Sciences, Sari Agricultural Sciences and Natural Resources University, Sari, Iran | ||
| چکیده [English] | ||
| Lead contamination of water resources as an environmental challenge requires the development of highly efficient decontamination methods such as the use of efficient, non-toxic and low-cost adsorbents. This study was conducted to compare the performance of rice husk biochar (RHB) and layered double hydroxides (Mg/Al-LDH) in removing lead from aqueous solutions. In this study, biochar was prepared from the pyrolysis of rice straw and stubble residues at 500°C under limited oxygen conditions and magnesium/aluminum layered double hydroxides at a ratio of 2:1 by co-precipitation method. The evaluation of parameters including adsorption kinetics, isotherm, and the initial solution pH on lead adsorption was performed. According to the results, kinetic studies showed that lead adsorption by RHB and LDH reached equilibrium in 60 and 240 min, respectively and the pseudo-second-order kinetic model showed high ability to predict the adsorption kinetics. with the increasing of initial solution pH, lead adsorption by both adsorbents increased. The Langmuir models showed high ability to predict the lead adsorption behavior by the adsorbents. The maximum lead adsorption capacity by RHB and LDH was 297.83 and 173.46 mg/g, respectively. The results of this study confirm that rice husk biochar can be considered a superior, low – cost, non – toxic and environmentally friendly option for the decontamination of lead from aquatic environments due to the high accessibility of active sites and stable performance over a wide pH range. | ||
| کلیدواژهها [English] | ||
| Contamination. Adsorbents, Isotherm, Kinetics, Langmuir | ||
| مراجع | ||
|
Abdelfattah, I., Ismail, A. A., Al Sayed, F., Almedolab, A., & Aboelghait, K. M. (2016). Biosorption of heavy metals ions in real industrial wastewater using peanut husk as efficient and cost effective adsorbent. Environmental Nanotechnology, Monitoring & Management, 6, 176-183. AFNOR, N. (1997). Analyse de l’eau. Lignes directrices pour le dosage du carbone organique total (TOC) et le carbone organique dissous (COD). NF EN, 1484, 90-102. Al-Ghouti, M. A., & Da'ana, D. A. (2020). Guidelines for the use and interpretation of adsorption isotherm models: A review. Journal of hazardous materials, 393, 122383. AlJaberi, F. Y., & Hawaas, Z. A. (2023). Electrocoagulation removal of Pb, Cd, and Cu ions from wastewater using a new configuration of electrodes. MethodsX, 10, 101951. Al-Maliky, E. A., Gzar, H. A., & Al-Azawy, M. G. (2021, September). Determination of point of zero charge (PZC) of concrete particles adsorbents. In IOP conference series: materials science and engineering (Vol. 1184, No. 1, p. 012004). IOP Publishing. Amin, M. T., Alazba, A. A., & Shafiq, M. (2018). Removal of copper and lead using banana biochar in batch adsorption systems: isotherms and kinetic studies. Arabian Journal for Science and Engineering, 43(11), 5711-5722. Anoob, F., Arachchi, S., Azamathulla, H. M., Al-mahbashi, N., & Rathnayake, U. (2024). Nanoadsorbents as an effective wastewater treatment candidate for pharmaceutical contaminants; towards sustainable policy development. Case Studies in Chemical and Environmental Engineering, 9, 100639. Azimzadeh, Y., Najafi, N., Reyhanitabar, A., Oustan, S., & Khataee, A. R. (2021). Modeling of phosphate removal by Mg-Al layered double hydroxide functionalized biochar and hydrochar from aqueous solutions. Iranian Journal of Chemistry and Chemical Engineering, 40(2), 565-579. Aziz, K. H. H., Mustafa, F. S., Hassan, M. A., Omer, K. M., & Hama, S. (2024). Biochar as green adsorbents for pharmaceutical pollution in aquatic environments: A review. Desalination, 583, 117725. Bahrami, H., Mejmarian, M., Jafari, H., & Rasekh, F. (2022). Synthesis of new Fe/Cr LDH for removal of Hg2+ ion from aqueous solutions and adsorption study using smartphone-based colorimetry. Environmental Nanotechnology, Monitoring & Management, 18, 100702. Bakhtiari, S., Salari, M., Shahrashoub, M., Zeidabadinejad, A., Sharma, G., & Sillanpää, M. (2024). A comprehensive review on green and eco-friendly nano-adsorbents for the removal of heavy metal ions: synthesis, adsorption mechanisms, and applications. Current Pollution Reports, 10(1), 1-39. Bashir, M., Mohan, C., Tyagi, S., & Annachhatre, A. (2022). Copper removal from aqueous solution using chemical precipitation and adsorption by Himalayan Pine Forest Residue as Biochar. Water Science and Technology, 86(3), 530-554. Bayar, J., Ali, N., Dong, Y., Ahmad, U., Anjum, M. M., Khan, G. R., ... & Ali, L. (2024). Biochar-based adsorption for heavy metal removal in water: a sustainable and cost-effective approach. Environmental geochemistry and health, 46(11), 428. Bayuo, J., Abukari, M. A., & Pelig-Ba, K. B. (2020). Desorption of chromium (VI) and lead (II) ions and regeneration of the exhausted adsorbent. Applied Water Science, 10(7), 171. Bolbol, H., Fekri, M., & Hejazi-Mehrizi, M. (2019). Layered double hydroxide–loaded biochar as a sorbent for the removal of aquatic phosphorus: behavior and mechanism insights. Arabian Journal of Geosciences, 12(16), 503. Carnier, R., Coscione, A. R., Abreu, C. A. D., Melo, L. C. A., & Silva, A. F. D. (2022). Cadmium and lead adsorption and desorption by coffee waste-derived biochars. Bragantia, 81, e0622. Chaijak, P., Michu, P., Thipraksa, J., & Kongthong, A. (2023). Biochar derived from the husk and straw of rice (Oryza sativa l.) produced via low-temperature pyrolysis as an effective adsorbent for pb (ii) removal. Pollution, 9(4), 1666-1675. Chaukura, N., Murimba, E. C., & Gwenzi, W. (2017). Sorptive removal of methylene blue from simulated wastewater using biochars derived from pulp and paper sludge. Environmental Technology & Innovation, 8, 132-140. Chen, G., Wang, C., Tian, J., Liu, J., Ma, Q., Liu, B., & Li, X. (2020). Investigation on cadmium ions removal from water by different raw materials-derived biochars. Journal of Water Process Engineering, 35, 101223. Cheng, X., Deng, J., Li, X., Wei, X., Shao, Y., & Zhao, Y. (2022). Layered double hydroxides loaded sludge biochar composite for adsorptive removal of benzotriazole and Pb (II) from aqueous solution. Chemosphere, 287, 131966. Cui, Q., Jiao, G., Zheng, J., Wang, T., Wu, G., & Li, G. (2019). Synthesis of a novel magnetic Caragana korshinskii biochar/Mg–Al layered double hydroxide composite and its strong adsorption of phosphate in aqueous solutions. RSC advances, 9(32), 18641-18651. Dhokpande, S. R., Deshmukh, S. M., Khandekar, A., & Sankhe, A. (2024). A review outlook on methods for removal of heavy metal ions from wastewater. Separation and Purification Technology, 350, 127868. Edet, U. A., & Ifelebuegu, A. O. (2020). Kinetics, isotherms, and thermodynamic modeling of the adsorption of phosphates from model wastewater using recycled brick waste. Processes, 8(6), 665. Foo, K. Y., & Hameed, B. H. (2010). Insights into the modeling of adsorption isotherm systems. Chemical engineering journal, 156(1), 2-10. Gao, L., Li, Z., Yi, W., Li, Y., Zhang, P., Zhang, A., & Wang, L. (2021). Impacts of pyrolysis temperature on lead adsorption by cotton stalk-derived biochar and related mechanisms. Journal of Environmental Chemical Engineering, 9(4), 105602. Gautam, A. K., Markandeya, Singh, N. B., Shukla, S. P., & Mohan, D. (2020). Lead removal efficiency of various natural adsorbents (Moringa oleifera, Prosopis juliflora, peanut shell) from textile wastewater. SN Applied Sciences, 2(2), 288. Guo, J., Kong, S., Lian, Y., & Zhao, M. (2024). Recent bio-applications of covalent organic framework-based nanomaterials. Chemical Communications, 60(8), 918-934. Hadjar, H., Mammar, A. C., Harouche, T., Yahia, T., & Kichou, N. (2025). Design of Mg–Al layered double hydroxides for lead capture from polluted water: kinetics, isoelectric point, and pH effect. International Journal of Environmental Science and Technology, 22(1), 171-188. Hameed, R., Abbas, A., Lou, J., Khattak, W. A., Roha, B., Iqbal, B., ... & Zhao, X. (2024). Synthesis of biochar-ZnAl-layered double hydroxide composite for effective heavy metal adsorption: Exploring mechanisms and structural transformations. Journal of Environmental Chemical Engineering, 12(3), 112687. Hamzenejad Taghlidabad, R., Sepehr, E., Khodaverdiloo, H., Samadi, A., & Rasouli-Sadaghiani, M. H. (2020). Characterization of cadmium adsorption on two cost-effective biochars for water treatment. Arabian journal of geosciences, 13(12), 448. Ho Nguyen Nhat Ha, H. N. N. H., Nguyen Thi Kim Phuong, N. T. K. P., Tran Boi An, T. B. A., Nguyen Thi Mai Tho, N. T. M. T., Tran Ngoc Thang, T. N. T., Bui Quang Minh, B. Q. M., & Cao Van Du, C. V. D. (2016). Arsenate removal by layered double hydroxides embedded into spherical polymer beads: batch and column studies. Hornung, A., Stenzel, F., & Grunwald, J. (2024). Biochar—just a black matter is not enough. Biomass Conversion and Biorefinery, 14(5), 5889-5900. Johnstona, A. L., Lesterb, E., Williamsb, O., & Gomesa, R. L. Impacts of Multipollutants on Sulfonamide Antibiotic Adsorptive Removal from Water Matrices using Layered Double Hydroxides. Khalil, A. K., Dweiri, F., Almanassra, I. W., Chatla, A., & Atieh, M. A. (2022). Mg-Al layered double hydroxide doped activated carbon composites for phosphate removal from synthetic water: Adsorption and thermodynamics studies. Sustainability, 14(12), 6991. Kumkum, P., & Kumar, S. (2024). A review on biochar as an adsorbent for Pb (II) removal from water. Biomass, 4(2), 243-272. Kwak JinHyeob, K. J., Islam, M. S., Wang SiYuan, W. S., Ashagre, F., Naeth, M. A., El-Din, M. G., & Chang, S. X. (2019). Biochar properties and lead (II) adsorption capacity depend on feedstock type, pyrolysis temperature, and steam activation. Li, H., Dong, X., da Silva, E. B., de Oliveira, L. M., Chen, Y., & Ma, L. Q. (2017). Mechanisms of metal sorption by biochars: Biochar characteristics and modifications. Chemosphere, 178, 466-478. Li, J., Shen, F., Yang, G., Zhang, Y., Deng, S., Zhang, J., ... & Mei, Z. (2018). Valorizing rice straw and its anaerobically digested residues for biochar to remove Pb (II) from aqueous solution. International Journal of Polymer Science, 2018(1), 2684962. Liu, X., Li, G., Chen, C., Zhang, X., Zhou, K., & Long, X. (2022). Banana stem and leaf biochar as an effective adsorbent for cadmium and lead in aqueous solution. Scientific reports, 12(1), 1584. Liu, Y., Chen, Y., Li, Y., Chen, L., Jiang, H., Jiang, L., ... & Chen, Y. (2023). Elaborating the mechanism of lead adsorption by biochar: Considering the impacts of water-washing and freeze-drying in preparing biochar. Bioresource Technology, 386, 129447. Ma, X., Li, S., Ren, H., Zhang, Y., & Ma, Z. (2022). Egg white-mediated fabrication of Mg/Al-LDH-hard biochar composite for phosphate adsorption. Molecules, 27(24), 8951. Maftouh, A., El Fatni, O., Ben Moussa, A., Boukir, F., & Noor us Subha, W. (2024). Heavy metals in the ecosystem; sources and their effects. In Heavy metal remediation: Sustainable nexus approach (pp. 27-44). Cham: Springer Nature Switzerland. Mahdi, Z., Yu, Q. J., & El Hanandeh, A. (2018). Removal of lead (II) from aqueous solution using date seed-derived biochar: batch and column studies. Applied Water Science, 8(6), 181. Mahmoudi, S., Chemat-Djenni, Z., Bouguettoucha, A., Guediri, A., Chebli, D., & Gil, A. (2022). Removal of Pb (II) from aqueous solutions by new layered double hydroxides adsorbent MgCuCaAl-LDH: Free Gibbs energy, entropy and internal energy studies. Inorganic Chemistry Communications, 144, 109910. Mbui, D., Njomo, N., Gitita, M., & Ndekei, A. (2021). Synthesis and characterization of rice husk biochar and its application in the adsorption studies of lead and copper. International Research Journal of Pure and Applied Chemistry, 22(4), 36-50. Mo, W., He, C., Yang, Y., Cheng, B., Yang, J., & Huang, Y. (2024). Adsorption behavior of Mg–Al layered double hydroxide on Pb (Ⅱ), Zn (Ⅱ), Cd (Ⅱ), and As (V) coexisting in aqueous solution. Materials Today Sustainability, 27, 100861. Nagaraju, K., Prasad, T. N. V. K. V., Naidu, M. V. S., Chari, M. S., Ramu, Y. R., & Murthy, B. R. (2023). Exploring the benefits of rice husk waste: synthesis and characterization of biochar and nanobiochar for agricultural and environmental sustainability. International Journal of Environment and Climate Change, 13(9), 715-725. Nguyen, D. A., Nguyen, D. V., Jeong, G., Asghar, N., & Jang, A. (2023). Critical evaluation of hybrid metal–organic framework composites for efficient treatment of arsenic–contaminated solutions by adsorption and membrane–separation process. Chemical Engineering Journal, 461, 141789. Nogueira, K. A., Cecilia, J. A., Santos, S. O., Aguiar, J. E., Vilarrasa-Garcia, E., Rodriguez-Castellon, E., ... & Silva Jr, I. J. (2016). Adsorption behavior of bovine serum albumin on Zn–Al and Mg–Al layered double hydroxides. Journal of Sol-Gel Science and Technology, 80(3), 748-758. Nzediegwu, C., Naeth, M. A., & Chang, S. X. (2021). Lead (II) adsorption on microwave-pyrolyzed biochars and hydrochars depends on feedstock type and production temperature. Journal of hazardous materials, 412, 125255. Pinthong, P., Praserthdam, P., & Jongsomjit, B. (2019). Effect of calcination temperature on Mg-Al layered double hydroxides (LDH) as promising catalysts in oxidative dehydrogenation of ethanol to acetaldehyde. Journal of oleo science, 68(1), 95-102. Rafiq, S., Wongrod, S., & Vinitnantharat, S. (2023). Adsorption kinetics of cadmium and lead by biochars in single-and bisolute brackish water systems. ACS omega, 8(48), 45262-45276. Ruebner, R. L., Hooper, S. R., Parrish, C., Furth, S. L., & Fadrowski, J. J. (2019). Environmental lead exposure is associated with neurocognitive dysfunction in children with chronic kidney disease. Pediatric nephrology, 34(11), 2371-2379. Sakhiya, A. K., Vijay, V. K., & Kaushal, P. (2022). Efficacy of rice straw derived biochar for removal of Pb+ 2 and Zn+ 2 from aqueous: Adsorption, thermodynamic and cost analysis. Bioresource Technology Reports, 17, 100920. Shafiq, M., Alazba, A. A., & Amin, M. T. (2023). Preparation of ZnMgAl-layered double hydroxide and rice husk biochar composites for Cu (II) and Pb (II) ions removal from synthetic wastewater. Water, 15(12), 2207. Shahriyari, J., Rezaei, M. R., Kamani, H., & SAYADI, A. M. H. (2020). Carcinogenic and non-carcinogenic risk assessment of heavy metals in drinking tap water in Zabol city, Iran. Su, X., Chen, Y., Li, Y., Li, J., Song, W., Li, X., & Yan, L. (2022). Enhanced adsorption of aqueous Pb (II) and Cu (II) by biochar loaded with layered double hydroxide: Crucial role of mineral precipitation. Journal of Molecular Liquids, 357, 119083. Sun, X., Hu, T., Sun, Y., Gao, X., Cao, Z., Liu, Y., ... & Li, L. (2023). Flower-like spherical ZnCdS/Bi2WO6/ZnAl-LDH with dual type II heterostructure as a photocatalyst for efficient photocatalytic degradation and hydrogen production. Journal of Physics and Chemistry of Solids, 183, 111650. Vithanage, M., Ashiq, A., Ramanayaka, S., & Bhatnagar, A. (2020). Implications of layered double hydroxides assembled biochar composite in adsorptive removal of contaminants: Current status and future perspectives. Science of The Total Environment, 737, 139718. Wang, S., Gao, B., Li, Y., Zimmerman, A. R., & Cao, X. (2016). Sorption of arsenic onto Ni/Fe layered double hydroxide (LDH)-biochar composites. Rsc Advances, 6(22), 17792-17799. Wang, J., & Guo, X. (2023). Adsorption kinetics and isotherm models of heavy metals by various adsorbents: An overview. Critical Reviews in Environmental Science and Technology, 53(21), 1837-1865. Weber, T. W., & Chakravorti, R. K. (1974). Pore and solid diffusion models for fixed‐bed adsorbers. AIChE Journal, 20(2), 228-238. Wołowicz, A., Staszak, K., & Hubicki, Z. (2023). Effect of anionic surfactants on the heavy metal ions removal by adsorption onto ion exchangers-batch and column studies. Journal of Water Process Engineering, 53, 103792. Woolf, D., Lehmann, J., Cowie, A., Cayuela, M. L., Whitman, T., & Sohi, S. (2018). Biochar for climate change mitigation. Soil and climate, 219-248. Xu, Z., Hu, Y., Guo, Z., Xiao, X., Peng, C., & Zeng, P. (2022). Optimizing pyrolysis temperature of contaminated rice straw biochar: Heavy metal (loid) deportment, properties evolution, and Pb adsorption/immobilization. Journal of Saudi Chemical Society, 26(2), 101439. Yu, S., Wang, X., Chen, Z., Wang, J., Wang, S., Hayat, T., & Wang, X. (2017). Layered double hydroxide intercalated with aromatic acid anions for the efficient capture of aniline from aqueous solution. Journal of Hazardous Materials, 321, 111-120. Zhan, W., Gao, L., Fu, X., Siyal, S. H., Sui, G., & Yang, X. (2019). Green synthesis of amino-functionalized carbon nanotube-graphene hybrid aerogels for high performance heavy metal ions removal. Applied Surface Science, 467, 1122-1133. Zhang, F., Song, Y., Song, S., Zhang, R., & Hou, W. (2015). Synthesis of magnetite–graphene oxide-layered double hydroxide composites and applications for the removal of Pb (II) and 2, 4-dichlorophenoxyacetic acid from aqueous solutions. ACS applied materials & interfaces, 7(13), 7251-7263. Zhang, F., Zhang, B., Han, D., Wu, L., & Hou, W. (2021). Preparation of composite soybean straw-based materials by LDHs modifying as a solid sorbent for removal of Pb (II) from water samples. Open Chemistry, 19(1), 726-734. Zhao, D., Sheng, G., Hu, J., Chen, C., & Wang, X. (2011). The adsorption of Pb (II) on Mg2Al layered double hydroxide. Chemical Engineering Journal, 171(1), 167-174. Zhou, H., Jiang, Z., Wei, S., & Liang, J. (2018). Adsorption of Cd (II) from aqueous solutions by a novel layered double hydroxide FeMnMg-LDH. Water, Air, & Soil Pollution, 229(3), 78. Zhu, M., Bian, Z., & Zhao, C. (Eds.). (2022). Persulfate-based Oxidation Processes in Environmental Remediation (Vol. 7). Royal Society of Chemistry. Zubair, M., Manzar, M. S., Mu'azu, N. D., Anil, I., Blaisi, N. I., & Al-Harthi, M. A. (2020). Functionalized MgAl-layered hydroxide intercalated date-palm biochar for Enhanced Uptake of Cationic dye: Kinetics, isotherm and thermodynamic studies. Applied Clay Science, 190, 105587. | ||
|
آمار تعداد مشاهده مقاله: 50 تعداد دریافت فایل اصل مقاله: 46 |
||