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H2O2 Oxidation of Pre-Coagulated Semi Aerobic Leachate | ||
International Journal of Environmental Research | ||
مقاله 4، دوره 4، شماره 2، تیر 2010، صفحه 209-216 اصل مقاله (105.86 K) | ||
شناسه دیجیتال (DOI): 10.22059/ijer.2010.11 | ||
نویسندگان | ||
H. Abdul Aziz1؛ A. Omran* 2؛ W. R. Zakaria1 | ||
1School of Civil Engineering, 14300, Nibong Tebal, Universiti Sains, Malaysia | ||
2School of Housing, Building and Planning, 11800, Minden, Universiti Sains, Malaysia | ||
چکیده | ||
Heavily polluted wastewater from sanitary landfill presents the leachate characteristics that need special treatment and disposal. Concentration of chemical oxygen demand (COD), ammonia nitrogen (NH3-N), heavy metal and other pollutant content are often larger than standard requirement after applying biological/physico-chemical treatment.Thus, the combination of coagulationflocculation and chemical oxidation treatment has been investigated. Using the jar-test procedure and stirrer, the physico-chemical conditions were optimized. It concerns the most effective coagulant between ferric chloride (FeCl3) and poly-aluminum chloride (PACl), the optimal pH and the H2O2 as the most effective chemical oxidant. The optimum pH and dosage of PACl and FeCl3 were obtained as 7 and 2.0 g/L, 5 and 1.0 g/L respectively. Iron salts were proved to be more efficient than aluminum ones, resulting in COD reduction (up to 59%) whereas the corresponding values using alum was lower (50%). The optimum pH and dosage of PACl and ferric chloride for optimum oxidation process was; 300 mg/L at pH7 and 300 mg/L at pH 6 respectively. Oxidation process gave significant effect to the removal of suspended solids and turbidity (up to 94%) using supernatant contain with ion Fe3+ at pH 7. | ||
کلیدواژهها | ||
Alum؛ Coagulation and flocculation؛ Ferric chloride؛ Hydrogen peroxide؛ Oxidation | ||
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