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Farzaneh, F.. (1390). Immobilization of Cu(II)-Histidine Complex on Al-MCM-41 as Catalyst for Epoxidation of Alkenes. , 23(1), 29-36.
F. Farzaneh. "Immobilization of Cu(II)-Histidine Complex on Al-MCM-41 as Catalyst for Epoxidation of Alkenes". , 23, 1, 1390, 29-36.
Farzaneh, F.. (1390). 'Immobilization of Cu(II)-Histidine Complex on Al-MCM-41 as Catalyst for Epoxidation of Alkenes', , 23(1), pp. 29-36.
Farzaneh, F.. Immobilization of Cu(II)-Histidine Complex on Al-MCM-41 as Catalyst for Epoxidation of Alkenes. , 1390; 23(1): 29-36.

Immobilization of Cu(II)-Histidine Complex on Al-MCM-41 as Catalyst for Epoxidation of Alkenes

Journal of Sciences, Islamic Republic of Iran
مقاله 4، دوره 23، شماره 1، خرداد 2012، صفحه 29-36    اصل مقاله (414.06 K)
نویسنده
F. Farzaneh
University of Alzahra
چکیده
Cu(II) complex with L-histidine (His) ligand, immobilized within Al-MCM-41, designated as Cu(His)2/Al-MCM-41 was prepared and characterized by powder X-ray diffraction (XRD), nitrogen adsorption desorption, FTIR, UV-Vis and chemical analysis techniques. The surface area and pore volume were found to decrease after immobilization of Cu(II) complex on Al-MCM-41. It was found that Cu(His)2/Al-MCM-41 catalyze the oxidation of some alkenes such as norbornene and trans-stilbene with tert-butylhydroperoxide (TBHP) with high activity and selectivity to the corresponding epoxides. It was concluded that the Al-MCM-41 nanoreactors is a suitable support for immobilization of biomimetic molecules. Particularly significant is that no desorption was observed during the course of reactions.
کلیدواژه‌ها
Al-MCM-41؛ Histidine؛ Copper complex؛ Epoxidation
عنوان مقاله [English]
Immobilization of Cu(II)-Histidine Complex on Al-MCM-41 as Catalyst for Epoxidation of Alkenes
نویسندگان [English]
F. Farzaneh
چکیده [English]
Cu(II) complex with L-histidine (His) ligand, immobilized within Al-MCM-41, designated as Cu(His)2/Al-MCM-41 was prepared and characterized by powder X-ray diffraction (XRD), nitrogen adsorption desorption, FTIR, UV-Vis and chemical analysis techniques. The surface area and pore volume were found to decrease after immobilization of Cu(II) complex on Al-MCM-41. It was found that Cu(His)2/Al-MCM-41 catalyze the oxidation of some alkenes such as norbornene and trans-stilbene with tert-butylhydroperoxide (TBHP) with high activity and selectivity to the corresponding epoxides. It was concluded that the Al-MCM-41 nanoreactors is a suitable support for immobilization of biomimetic molecules. Particularly significant is that no desorption was observed during the course of reactions.
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