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Lokwani, L.. (1391). Liquid-Liquid Extraction Study of Sodium and Potassium Ions by a Series of Non Cyclic Ionophores Composed of Furan Units. , 23(2), 123-128.
L. Lokwani. "Liquid-Liquid Extraction Study of Sodium and Potassium Ions by a Series of Non Cyclic Ionophores Composed of Furan Units". , 23, 2, 1391, 123-128.
Lokwani, L.. (1391). 'Liquid-Liquid Extraction Study of Sodium and Potassium Ions by a Series of Non Cyclic Ionophores Composed of Furan Units', , 23(2), pp. 123-128.
Lokwani, L.. Liquid-Liquid Extraction Study of Sodium and Potassium Ions by a Series of Non Cyclic Ionophores Composed of Furan Units. , 1391; 23(2): 123-128.

Liquid-Liquid Extraction Study of Sodium and Potassium Ions by a Series of Non Cyclic Ionophores Composed of Furan Units

Journal of Sciences, Islamic Republic of Iran
مقاله 3، دوره 23، شماره 2، شهریور 2012، صفحه 123-128    اصل مقاله (362.01 K)
نویسنده
L. Lokwani
1Department of Chemistry, Faculty of Sciences, Govt. College
چکیده
A new series of noncyclic ionophores containing two to four furan units (Ia to IIIb) i.e. 1,1-difurylethane (Ia), 2,5-bis(methylfurfuryl)furan (IIa) and 1,1’ ethyledenebis[5-(methylfurfuryl)furan] (IIIa), 2,2-difurylpropane (Ib), 2,5-bis (dimethylfurfuryl)furan(IIb), 2,2’-isopropylidenebis[5-(dimethylfurfuryl)furan] (IIIb) have been synthesized by the condensation of furan with acetaldehyde and acetone in ethanol separately in the presence of concentrated hydrochloric acid. These ionophores were used for the extraction of alkali metal ions from aqueous to organic phase in chloroform membrane using picrate, dinitrophenolate and orthonitrophenolate salts. All ionophores of series (a) and (b) extract K+ selectively over Na+ and ligands IIa and IIb show the best extraction efficiency for K+ among these series. Among anions, orthonitrophenolate is found to be the best in comparison to dinitrophenolate and picrate during extraction. Thus, we can control the extraction of cations by altering anion.
کلیدواژه‌ها
Dinitrophenolate؛ extraction؛ Orthonitrophenolate؛ Noncyclic ionophores؛ Picrate
عنوان مقاله [English]
Liquid-Liquid Extraction Study of Sodium and Potassium Ions by a Series of Non Cyclic Ionophores Composed of Furan Units
نویسندگان [English]
L. Lokwani
چکیده [English]
A new series of noncyclic ionophores containing two to four furan units (Ia to IIIb) i.e. 1,1-difurylethane (Ia), 2,5-bis(methylfurfuryl)furan (IIa) and 1,1’ ethyledenebis[5-(methylfurfuryl)furan] (IIIa), 2,2-difurylpropane (Ib), 2,5-bis (dimethylfurfuryl)furan(IIb), 2,2’-isopropylidenebis[5-(dimethylfurfuryl)furan] (IIIb) have been synthesized by the condensation of furan with acetaldehyde and acetone in ethanol separately in the presence of concentrated hydrochloric acid. These ionophores were used for the extraction of alkali metal ions from aqueous to organic phase in chloroform membrane using picrate, dinitrophenolate and orthonitrophenolate salts. All ionophores of series (a) and (b) extract K+ selectively over Na+ and ligands IIa and IIb show the best extraction efficiency for K+ among these series. Among anions, orthonitrophenolate is found to be the best in comparison to dinitrophenolate and picrate during extraction. Thus, we can control the extraction of cations by altering anion.
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