EFFICIENT PHOSPHOROUS-SULFUR BOND REDUCTION IN BICYCLIC THIAPHOSPHORANES WITH TRI-n-BUTYLTIN HYDRIDE | ||
| Journal of Sciences, Islamic Republic of Iran | ||
| مقاله 3، دوره 4، شماره 1، 1993 اصل مقاله (148.79 K) | ||
| چکیده | ||
| High yield photolytic reduction of a series of thiaphosphoranes Z p SR to give Z p H with UV-light-induced tri-n-butyltin hydride through phosphoranyl radical Z p is described. This reaction is inhibited by a-methylstyrene and initiated by a radical initiator such as azobisisobutyronitrile | ||
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