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Photochemical Rearrangement of 8- methyl Spiro [2.5] oct-7-en-4-one to 4-methyl Spiro [2.5] oct-4-en-6-one

Journal of Sciences, Islamic Republic of Iran
مقاله 7، دوره 1، شماره 1، 1989    اصل مقاله (308.01 K)
چکیده
Irradiation of &methyl spiro [2.5] oct-7-en-4-one through its singlet excited
state resulted in the formation of 4-methyl spirO [2.5] oct-4-en -6-one. We have
used the cyclopropyl moiety in the molecule as a probe to study the operating
mechanism in the photochemistry of ?, ?-unsaturated compounds. The results
showed that this photoisomerization probably occurs through a concerted
process.
آمار
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