A KINETIC STUDY OF THE DECOMPOSITION OF PYRIDINE CHROMIUM (VI) PEROXIDE WITH ALCOHOLS | ||
| Journal of Sciences, Islamic Republic of Iran | ||
| مقاله 6، دوره 4، شماره 4، 1993 اصل مقاله (380.48 K) | ||
| چکیده | ||
| A kinetic study of the decomposition of pyridine chromium peroxide with methanol, ethanol, propanol and isopropanol has been made over the temperature range 25 to 40°C. It is found that the ligand exchange stage is the rate determining step in the oxidation process. The activation parameters E , ?H‡ and ?S‡ for the reactions are determined. It is believed that the peroxide linkage is primarily responseble for the oxidation process | ||
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