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PREPARATION AND MOLECULAR STRUCTURE OF BIS (TETRAMETHYLETHYLENEDIAMINE) COPPER(I) DICHLORO CUPRATE(I) , [Cu (TMEDA) ] [CuC1 ] | ||
Journal of Sciences, Islamic Republic of Iran | ||
مقاله 13، دوره 4، شماره 4، اسفند 1993 اصل مقاله (142.17 K) | ||
چکیده | ||
A complex of N, N, N', N', -tetramethylated ethylenediamine, TMEDA, with CuCI is prepared. The crystal and molecular structure of this complex is characterized by a single-crystal X-ray diffraction study. The complex is found to contain [Cu (TMEDA) ] cation which is nearly tetrahedral and the [CuCI ) anion is linear which Cu lies on a center of symmetry. Crystals are monoclinic space group P2 / n with four molecules/ unit cell of dimensions a = 9.240 (4), b = 14.930 (3), c = 14.288 (5) ? and B= 97.02 (3)?. The final R value is 0.045 for 3808 reflections measured. | ||
عنوان مقاله [English] | ||
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چکیده [English] | ||
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