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THERMODYNAMIC STUDIES ON THE INTERACTION BETWEEN DODECYL TRIMETHYL AMMONIUM BROMIDE AND HISTONE H A | ||
| Journal of Sciences, Islamic Republic of Iran | ||
| مقاله 2، دوره 5، شماره 1، شهریور 1994 اصل مقاله (219.53 K) | ||
| چکیده | ||
| The thermodynamic parameters of interaction between calf thymus histone H A and dodecyl trimethyl ammonium bromide (DTAB), a cationic surfactant, in aqueous solutions of pH 3.2, 6.4 and 10.0 were measured over a wide range of DTAB concentrations by equilibrium dialysis at 27°C and 37°C and are discussed. The data are used to determine the free energy from the Wyman binding potential theoretical model, and the enthalp y of interaction from the temperature dependence of the equilibrium constants using the van't Hoff relation. The data obtained for H A-DTAB are compared with the corresponding data for H A and sodium n-dodecyl sulphate (SDS) complexes. The difference between the cationic and anionic surfactants interaction in regard to histone H A is discussed | ||
| عنوان مقاله [English] | ||
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| چکیده [English] | ||
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