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. (1373). THE KINETICS OF HYDROLYSIS OF TRANS-DIFLUOROTETRAMMINECHROMIUM (111) ION IN VARIOUS CONCENTRATED ACID SOLUTIONS. , 5(1), -.
. "THE KINETICS OF HYDROLYSIS OF TRANS-DIFLUOROTETRAMMINECHROMIUM (111) ION IN VARIOUS CONCENTRATED ACID SOLUTIONS". , 5, 1, 1373, -.
. (1373). 'THE KINETICS OF HYDROLYSIS OF TRANS-DIFLUOROTETRAMMINECHROMIUM (111) ION IN VARIOUS CONCENTRATED ACID SOLUTIONS', , 5(1), pp. -.
. THE KINETICS OF HYDROLYSIS OF TRANS-DIFLUOROTETRAMMINECHROMIUM (111) ION IN VARIOUS CONCENTRATED ACID SOLUTIONS. , 1373; 5(1): -.

THE KINETICS OF HYDROLYSIS OF TRANS-DIFLUOROTETRAMMINECHROMIUM (111) ION IN VARIOUS CONCENTRATED ACID SOLUTIONS

Journal of Sciences, Islamic Republic of Iran
مقاله 9، دوره 5، شماره 1، شهریور 1994    اصل مقاله (381.97 K)
چکیده
The rate of hydrolysis of trans -[Cr(NH ) F ] was obtained as a function of acid
concentsation in perchloric, sulfuric and nitric acid at 3Q°C. The results have been
analyzed by the treatment of Bunnett and Olsen. Values of the parameter ?in Olsen
equation are consistent with the participation of water as a proton-wansfer agent in the rate-determining step. The Arrhenius plot for perchloric acid was linear, with an
activation energy of 19.8 ± 0.8 KCal K mole .
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چکیده [English]
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