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THE KINETICS OF HYDROLYSIS OF TRANS-DIFLUOROTETRAMMINECHROMIUM (111) ION IN VARIOUS CONCENTRATED ACID SOLUTIONS | ||
Journal of Sciences, Islamic Republic of Iran | ||
مقاله 9، دوره 5، شماره 1، شهریور 1994 اصل مقاله (381.97 K) | ||
چکیده | ||
The rate of hydrolysis of trans -[Cr(NH ) F ] was obtained as a function of acid concentsation in perchloric, sulfuric and nitric acid at 3Q°C. The results have been analyzed by the treatment of Bunnett and Olsen. Values of the parameter ?in Olsen equation are consistent with the participation of water as a proton-wansfer agent in the rate-determining step. The Arrhenius plot for perchloric acid was linear, with an activation energy of 19.8 ± 0.8 KCal K mole . | ||
عنوان مقاله [English] | ||
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چکیده [English] | ||
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آمار تعداد مشاهده مقاله: 935 تعداد دریافت فایل اصل مقاله: 805 |