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. (1369). SPECTROPHOTOMETRIC DETERMI NATION OF OSMIUM (VIII) WITH 1-HYDROXY 2- PYRIDINE - THIONE (SODIUM SALT) AS A REAGENT. , 1(4), -.
. "SPECTROPHOTOMETRIC DETERMI NATION OF OSMIUM (VIII) WITH 1-HYDROXY 2- PYRIDINE - THIONE (SODIUM SALT) AS A REAGENT". , 1, 4, 1369, -.
. (1369). 'SPECTROPHOTOMETRIC DETERMI NATION OF OSMIUM (VIII) WITH 1-HYDROXY 2- PYRIDINE - THIONE (SODIUM SALT) AS A REAGENT', , 1(4), pp. -.
. SPECTROPHOTOMETRIC DETERMI NATION OF OSMIUM (VIII) WITH 1-HYDROXY 2- PYRIDINE - THIONE (SODIUM SALT) AS A REAGENT. , 1369; 1(4): -.

SPECTROPHOTOMETRIC DETERMI NATION OF OSMIUM (VIII) WITH 1-HYDROXY 2- PYRIDINE - THIONE (SODIUM SALT) AS A REAGENT

Journal of Sciences, Islamic Republic of Iran
مقاله 4، دوره 1، شماره 4، آبان 1990    اصل مقاله (284.16 K)
چکیده
A spectrophotometric study of osmium (VIII) complex of 1-hydroxy 2- pyridine
thione (HPT) is presented. A red-violet complex, 0 s (HPT) is formed in a highly
acidic solution, and shows maximum absorbance at 500 nm with molar absorptivity
of 5.12 x 101. mol . cm . Beer's law is obeyed in the range of 3-60 ppm. Sandel's
sensitivity of the method is 0.37 ?g.cm per0.001 ab sorbance unit. V (V), Pt (IV),
Cu (II), Sn (IV), Cr (VI), and NO . interference. To overcome the interference and
improve the selectivity, the 0 s (VIII) as OsO isextracted inCC1 and theextracted
0s (VIII) is converted to the complex and measured spectrophotometrically. This
method reduces the number of interferences to V(V), Pt (IV), and NO -. The
method offers the advantages of simplicity, speed and high precision. A spot test for
the detection of traces of osmium is also presented
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