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Adsorption of Copper (II) Ions from Aqueous Solution onto Activated Carbon Prepared from Cane Papyrus | ||
Pollution | ||
مقاله 9، دوره 4، شماره 4، دی 2018، صفحه 649-662 اصل مقاله (901.92 K) | ||
نوع مقاله: Original Research Paper | ||
شناسه دیجیتال (DOI): 10.22059/poll.2018.249931.377 | ||
نویسنده | ||
M. J. Alatabe* | ||
Environmental Engineering Department, Faculty of Engineering, University of Mustansiriyah, Baghdad, P.O. Box: 14022, Baghdad, Iraq. | ||
چکیده | ||
The present study evaluates the suitability ofactivated carbon, prepared from Cane Papyrus, a plant that grows naturally and can be found quite easily, which serves as a biological sorbent for removal of Cu2+ ions from aqueous solutions. Fourier transform infra-red analysis for the activated carbon, prepared fromCane Papyrus confirms the presence of amino (–NH), carbonyl (–C=O), and hydroxyl (–OH) functional groups with Bath mode getting used to investigate the effects of the following parameters: adsorbent dosage (among the rates of 10, 20, and 30 g/L), pH values, Cu2+ initial concentration, and contact time. Results reveal higher efficiency (98%) of powdered adsorbent for removal of Cu2+ ions, which is found at pH=6 with 30 g/L activated carbon, prepared from Cane Papyrus, for a duration of 2 hours. The Freundlich isotherm model with linearized coefficient of 0.982 describes the adsorption process more suitably than the langmuir model, in which this rate equals to 0.899. Pseudo-second order kinetic equation best describes the kinetics of the reaction. Furthermore, it has been found that 0.5M HCl is a better desorbing agent than either 0.5 M NaOH or de-ionized water. The experimental data, obtained, demonstrate that the activated carbon prepared from Cane Papyrus can be used as a suitable adsorbent for Copper(II) ion removal from aqueous solutions. | ||
کلیدواژهها | ||
Natural Plants؛ Biosorbent؛ Activation؛ Removal Efficiency؛ kinetics | ||
مراجع | ||
Alatabe, M. J. (2012). Removal of lea Ions from Industrial waste Water. Journal of Environmental Studies, 9: 1-7.
Alatabe, M. J. and Alaa, A. (2017). Isotherm and Kinetics studies, Adsorption of Chromium(III) Ions from Wastewater Using Cane Papyrus. International Journal of Scientific Research in Science, Engineering and Technology, 3(6): 2394-4099. Baccar, R., Bouzid, J., Feki, M. and Montiel, A. (2009). Preparation of activated carbon from Tunisian olive-waste cakes and its application for adsorption of heavy metal ions. J. Hazard Mater, 162(2-3): 1522–1529.
Bouhamed, F., Elouear, Z., Ouddane, B. and Bouzid, J. (2016). Multi-component adsorption of copper, nickel and zinc from aqueous solutions onto activated carbon prepared from date stone. Environmental Science and Pollution Research, 23(16): 15801–15806.
Cheung, C.W., Porter, J. F. and McKay, G. (2001). Sorption kinetic analysis for the removal of cadmium ions from effluents using bone char. Water Research, 35(3): 605-621.
Chen, H., Dai, G., Zhao, J., Zhong, A., Wu, J. and Yan, H. (2010). Removal of copper(II) ions by a biosorbent —Cinnamomum camphora leaves powder. J. Hazard Mater, 177(1-3): 228–236.
Delaila, T.N., Luqman, C.A., Zawani, Z. and Abdul, R.S. (2008). Adsorption of copper from aqueous solution by Elais Guineesis kernel activated carbon. J. Eng. Sci. Technol. 3: 180–189.
Donohue, J. (2004). Copper in Drinking-water, World Health Organization.
Dorris, K. L., Zhang, Y., Shukla, S.S., Yu, B. and Shukla, A. (2000). The removal of heavy metal from aqueous solution by sawdust adsorption removal of copper. J. hazard mater, 80(1-3): 33- 42.
Freundlich (1906), HMF Over the adsorption in solution. J. Phys. Chem., 57(3): 85–471.
Futalan, C.M., Kan, C.C., Dalida, M.L., Hsien, K.J., Pascua, C. and Wan, M.W. (2011). Comparative and competitive adsorption of copper, lead, and nickel using chitosan immobilized on entonite. Carbohydr Polym, 83(2): 528–536.
Geographic Location: Middle East: Iran, Iraq, and Kuwait (2013) . "Mesopotamian Delta and Marshes". World Wide Fund for Nature. Retrieved .
Hameed, B.H., Ahmad, A.A. and Aziz, N. (2007). Isotherms, kinetics and thermodynamics of acid dye adsorption on activated palm ash. Chem. Eng. J., 133(1-3): 195–203.
Hanzlik, J., Jehlicka, J., Sebek, O., Weishauptova, Z. and Machovic, V. (2004). Multi-component adsorption of Ag(I), Cd(II) and Cu(II) by natural carbonaceous materials. Water Res., 38(8): 2178–2184.
Ho, Y.S. and Mckay, G. (1999). Competitive sorption of copper and nickel ions from aqueous solution using peat.Journal of the International Adsorption Society. Adsorption, 5(4): 409–417.
Inglezakis, V. J., Loizidou, M. M. and Grigoropoulou, H. P. (2004). Ion Exchange Studies on Natural and Modified Zeolites and the Concept of Exchange Site Accessibility. Journal of Colloid and Interface Science, 275 (2): 570-576. Langmuir, I. (1916).The constitution and fundamental properties of solids and liquids. J. Am. Chem. Soc.,38(11): 2221–2295. Langmuir, I. (1918). The adsorption of gases on plane surfaces of glass, mica and platinum. J. Am. Chem. Soc.,40(9): 1361-1403. Lin, S. H. and Wang, C. S.(2002). Treatment of high-strength phenolic wastewater by a new two-step method. Journal of Hazardous Materials, 90(2): 205-216.
Mukesh, P. and Thakur, L.S.(2013). Heavy Metal Cu, Ni and Zn: Toxicity, Health Hazards and their removal techniques by Low Cost Adsorbents: A Short Overview. International Journal of Plant, Animal and Environmental Sciences, 3(3): 143- 157.
Moselhy, K.M., Azzem, M.A. , Amer, A. and. Al–Prol, A.E.(2017). Adsorption of Cu(II) and Cd(II) from Aqueous Solution by Using Rice Husk. Adsorbent. Phys. Chem. Ind. J.,12(2): 109-122.
Patil, K.P., Patil, V.S., Nilesh, P. and Motiraya, V. (2012) . Adsorption of Copper (Cu2+) & Zinc (Zn2+) Metal Ion from Wastewater by Using Soybean Hulls and Sugarcane Bagasse as Adsorbent. International Journal of Scientific Research and Reviews, 1(2): 13-23.
Pehlivan, E., Altun, T. and Parlayici, Ş. (2012). Modified barley straw as a potential bio- sorbent for removal of copper ions from aqueous solution. Food Chem., 135(4): 2229–2234.
Prasad, M., Xu H.Y. and Saxena, S. (2008). Multi-component sorption of Pb(II), Cu(II) and Zn(II) onto low-cost mineral adsorbent. J. Hazard Mater, 154(1-3): 221–229.
Qin, F., Wen, B., Shan, X.Q., Xie, Y.N., Liu, T., Zhang, S.Z. and Khan, S.U. (2006). Mechanisms of competitive adsorption of Pb , Cu, and Cd on peat. Environ Pollut., 144(2): 669–680.
Smith, B.C.(2011). Fundamentals of Fourier Transform Infrared Spectroscopy, Second Edition, Taylor and Francis Group.
Veli, S. and Pekey, B. (2004) Removal of copper from aqueous solution by ion exchange resins. Fresen. Environ. Bull., 13(3b): 244–250.
Vernersson, T., Bonelli, P.R., Cerrela, E.G. and Cukierman, A.L. (2002). Arundo donax cane as a precursor for activated carbons preparation by phosphoric acid activation. Bioresour. Technol., 83(2): 95–104.
Xiao, B. and Thomas, K.M. (2004). Competitive adsorption of aqueous metal ions on an oxidized nanoporous activated carbon. Langmuir, 20(11):4566–4578.
Zhu, Y., Jun, H. and Wang, J. (2012). Competitive adsorption of Pb(II), Cu(II) and Zn(II) onto xanthate-modified magnetic chitosan. J. Hazard Mater, 221–222:155–161. | ||
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