سامانه پشتیبانی خدمات اطلاعات

  اخبار و اعلانات

 آمار

تعداد نشریات161
تعداد شماره‌ها6,466
تعداد مقالات69,886
تعداد مشاهده مقاله122,400,816
تعداد دریافت فایل اصل مقاله95,649,478
Fathyunes, Leila, khalil-Allafi, Jafar, Marashi-Najafi, Fatemeh. (1398). Effect of pulsed current densities on co-electrodeposition of Graphene Oxide/ Calcium-Phosphate coatings and their biocompatibility. , 52(1), 57-68. doi: 10.22059/JUFGNSM.2019.01.06
Leila Fathyunes; Jafar khalil-Allafi; Fatemeh Marashi-Najafi. "Effect of pulsed current densities on co-electrodeposition of Graphene Oxide/ Calcium-Phosphate coatings and their biocompatibility". , 52, 1, 1398, 57-68. doi: 10.22059/JUFGNSM.2019.01.06
Fathyunes, Leila, khalil-Allafi, Jafar, Marashi-Najafi, Fatemeh. (1398). 'Effect of pulsed current densities on co-electrodeposition of Graphene Oxide/ Calcium-Phosphate coatings and their biocompatibility', , 52(1), pp. 57-68. doi: 10.22059/JUFGNSM.2019.01.06
Fathyunes, Leila, khalil-Allafi, Jafar, Marashi-Najafi, Fatemeh. Effect of pulsed current densities on co-electrodeposition of Graphene Oxide/ Calcium-Phosphate coatings and their biocompatibility. , 1398; 52(1): 57-68. doi: 10.22059/JUFGNSM.2019.01.06

Effect of pulsed current densities on co-electrodeposition of Graphene Oxide/ Calcium-Phosphate coatings and their biocompatibility

Journal of Ultrafine Grained and Nanostructured Materials
مقاله 6، دوره 52، شماره 1، شهریور 2019، صفحه 57-68    اصل مقاله (1.9 M)
نوع مقاله: Research Paper
شناسه دیجیتال (DOI): 10.22059/JUFGNSM.2019.01.06
نویسندگان
Leila Fathyunes* 1؛ Jafar khalil-Allafi2؛ Fatemeh Marashi-Najafi2
1Department of Materials Science and Engineering, University of Bonab, Bonab, Iran.
2Research Center for Advanced Materials, Faculty of Materials Engineering, Sahand University of Technology, Tabriz, Iran.
چکیده
In this study, calcium-phosphate (Ca-P) and graphene oxide (GO)/ calcium-phosphate (Ca-P) coatings were electrodeposited with different pulsed current densities on TiO2 nanotubes. Results showed that the co-electrodeposition rate in the presence of GO, especially at low current densities of 2 and 5 mA/cm2, significantly decreased. This might be due to the large size of GO sheets as compared to the size of calcium and phosphate ions. The SEM micrographs revealed that the surface of the anodized titanium could not be completely covered with the GO/Ca-P coatings applied at such low current densities. However, producing a considerable amount of H2 gases at higher current densities of 10 and 15 mA/cm2 caused the formation of a coating with poor quality. Regarding this, increasing the off part of the pulsed current by changing duty cycle from 0.3 to 0.1 led to the co-electrodeposition of GO/Ca-P coating with an acceptable quality. The FTIR and micro-Raman analyses also demonstrated that the current density of 15 mA/cm2 was more favorable to apply the coating predominantly consisting of hydroxyapatite (HA) phase. At last, studying the ability of apatite mineralization in simulated body fluid (SBF) displayed that both Ca-P and GO/Ca-P coatings electrodeposited at the current density of 15 mA/cm2 and duty cycle of 0.1 are acceptable for biomedical applications.
کلیدواژه‌ها
Calcium Phosphate؛ Graphene oxide؛ Coating؛ Pulsed current densities؛ Co-electrodeposition؛ Biocompatibility
مراجع

1.            Parcharoen Y, Kajitvichyanukul P, Sirivisoot S, Termsuksawad P. Hydroxyapatite electrodeposition on anodized titanium nanotubes for orthopedic applications. Applied Surface Science. 2014;311:54-61.

2.            Blackwood DJ, Seah KHW. Galvanostatic pulse deposition of hydroxyapatite for adhesion to titanium for biomedical purposes. Materials Science and Engineering: C. 2010;30(4):561-5.

3.            Yan Y, Zhang X, Mao H, Huang Y, Ding Q, Pang X. Hydroxyapatite/gelatin functionalized graphene oxide composite coatings deposited on TiO2 nanotube by electrochemical deposition for biomedical applications. Applied Surface Science. 2015;329:76-82.

4.            Lee K, Jeong Y-H, Brantley WA, Choe H-C. Surface characteristics of hydroxyapatite films deposited on anodized titanium by an electrochemical method. Thin Solid Films. 2013;546:185-8.

5.            Raj V, Mumjitha MS. Fabrication of biopolymers reinforced TNT/HA coatings on Ti: Evaluation of its Corrosion resistance and Biocompatibility. Electrochimica Acta. 2015;153:1-11.

6.            Janković A, Eraković S, Vukašinović-Sekulić M, Mišković-Stanković V, Park SJ, Rhee KY. Graphene-based antibacterial composite coatings electrodeposited on titanium for biomedical applications. Progress in Organic Coatings. 2015;83:1-10.

7.            Fathyunes L, Khalil-Allafi J. Characterization and corrosion behavior of graphene oxide-hydroxyapatite composite coating applied by ultrasound-assisted pulse electrodeposition. Ceramics International. 2017;43(16):13885-94.

8.            Fathyunes L, Khalil-Allafi J, Moosavifar M. Development of graphene oxide/calcium phosphate coating by pulse electrodeposition on anodized titanium: Biocorrosion and mechanical behavior. Journal of the Mechanical Behavior of Biomedical Materials. 2019;90:575-86.

9.            Li M, Liu Q, Jia Z, Xu X, Cheng Y, Zheng Y, et al. Graphene oxide/hydroxyapatite composite coatings fabricated by electrophoretic nanotechnology for biological applications. Carbon. 2014;67:185-97.

10.          Mohajernia S, Hejazi S, Eslami A, Saremi M. Modified nanostructured hydroxyapatite coating to control the degradation of magnesium alloy AZ31 in simulated body fluid. Surface and Coatings Technology. 2015;263:54-60.

11.          Benea L, Mardare-Danaila E, Celis J-P. Increasing the tribological performances of Ti–6Al–4V alloy by forming a thin nanoporous TiO2 layer and hydroxyapatite electrodeposition under lubricated conditions. Tribology International. 2014;78:168-75.

12.          Fathyunes L, Khalil-Allafi J, Sheykholeslami SOR, Moosavifar M. Biocompatibility assessment of graphene oxide-hydroxyapatite coating applied on TiO 2 nanotubes by ultrasound-assisted pulse electrodeposition. Materials Science and Engineering: C. 2018;87:10-21.

13.          Fathyunes L, Khalil-Allafi J. Effect of employing ultrasonic waves during pulse electrochemical deposition on the characteristics and biocompatibility of calcium phosphate coatings. Ultrasonics Sonochemistry. 2018;42:293-302.

14.          Hovestad A, Janssen LJJ. Electroplating of Metal Matrix Composites by Codeposition of Suspended Particles. Modern Aspects of Electrochemistry: Springer-Verlag. p. 475-532.

15.          Walsh FC, Ponce de Leon C. A review of the electrodeposition of metal matrix composite coatings by inclusion of particles in a metal layer: an established and diversifying technology. Transactions of the IMF. 2014;92(2):83-98.

16.          Fathyunes L, Khalil-Allafi J. The effect of graphene oxide on surface features, biological performance and bio-stability of calcium phosphate coating applied by pulse electrochemical deposition. Applied Surface Science. 2018;437:122-35.

17.          Low CTJ, Wills RGA, Walsh FC. Electrodeposition of composite coatings containing nanoparticles in a metal deposit. Surface and Coatings Technology. 2006;201(1-2):371-83.

18.          Nasirpouri F. Electrodeposition of Nanostructured Materials. Springer Series in Surface Sciences: Springer International Publishing; 2017.

19.          Das MK, Li R, Qin J, Zhang X, Das K, Thueploy A, et al. Effect of electrodeposition conditions on structure and mechanical properties of Ni-W/diamond composite coatings. Surface and Coatings Technology. 2017;309:337-43.

20.          Vb S. An Overview on the Preparation, Characterization and Properties of Electrodeposited-Metal Matrix Nanocomposites. Nanoscience & Technology: Open Access. 2014;1(3).

21.          Daneshvar-Fatah F, Nasirpouri F. A study on electrodeposition of Ni-noncovalnetly treated carbon nanotubes nanocomposite coatings with desirable mechanical and anti-corrosion properties. Surface and Coatings Technology. 2014;248:63-73.

22.          Baradaran S, Moghaddam E, Basirun WJ, Mehrali M, Sookhakian M, Hamdi M, et al. Mechanical properties and biomedical applications of a nanotube hydroxyapatite-reduced graphene oxide composite. Carbon. 2014;69:32-45.

23.          Krishnamoorthy K, Veerapandian M, Yun K, Kim SJ. The chemical and structural analysis of graphene oxide with different degrees of oxidation. Carbon. 2013;53:38-49.

24.          Garskaite E, Gross K-A, Yang S-W, Yang TC-K, Yang J-C, Kareiva A. Effect of processing conditions on the crystallinity and structure of carbonated calcium hydroxyapatite (CHAp). CrystEngComm. 2014;16(19):3950.

25.          Utku FS, Seckin E, Goller G, Tamerler C, Urgen M. Carbonated hydroxyapatite deposition at physiological temperature on ordered titanium oxide nanotubes using pulsed electrochemistry. Ceramics International. 2014;40(10):15479-87.

26.          Baradaran S, Moghaddam E, Nasiri-Tabrizi B, Basirun WJ, Mehrali M, Sookhakian M, et al. Characterization of nickel-doped biphasic calcium phosphate/graphene nanoplatelet composites for biomedical application. Materials Science and Engineering: C. 2015;49:656-68.

27.          Gopi D, Indira J, Kavitha L. A comparative study on the direct and pulsed current electrodeposition of hydroxyapatite coatings on surgical grade stainless steel. Surface and Coatings Technology. 2012;206(11-12):2859-69.

28.          Kar A, Raja KS, Misra M. Electrodeposition of hydroxyapatite onto nanotubular TiO2 for implant applications. Surface and Coatings Technology. 2006;201(6):3723-31.

29.          Saremi M, Mohajernia S, Hejazi S. Controlling the degradation rate of AZ31 Magnesium alloy and purity of nano-hydroxyapatite coating by pulse electrodeposition. Materials Letters. 2014;129:111-3.

30.          Mahto TK, Chandra Pandey S, Chandra S, Kumar A, Sahu Sk. Hydroxyapatite conjugated graphene oxide nanocomposite: a new sight for significant applications in adsorption. RSC Advances. 2015;5(117):96313-22.

31.          Lobo AO, Corat MAF, Ramos SC, Matsushima JT, Granato AEC, Pacheco-Soares C, et al. Fast Preparation of Hydroxyapatite/Superhydrophilic Vertically Aligned Multiwalled Carbon Nanotube Composites for Bioactive Application. Langmuir. 2010;26(23):18308-14.

32.          Stappers L, Fransaer J. AFM Study of the Incorporation of Particles during Electrodeposition. Journal of The Electrochemical Society. 2007;154(11):D598.

33.          Stappers L, Fransaer J. Growth of Metal around Particles during Electrodeposition. Journal of The Electrochemical Society. 2006;153(7):C472.

 

آمار
تعداد مشاهده مقاله: 1,427
تعداد دریافت فایل اصل مقاله: 914


سامانه مدیریت نشریات علمی. قدرت گرفته از سیناوب