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Lotfi, v., Emamgholi, B., Bahrami, S. T., poorakbar, E.. (1398). Synthesis and Application of Bis[1,2-(4-aryl-2-alkyl-1H- inden-1-yl)]Ethane as an Efficient`Ligand for Preparation of Olefin Polymerization Catalysts. , 30(2), 135-142. doi: 10.22059/jsciences.2019.71749
v. Lotfi; B. Emamgholi; S. T. Bahrami; E. poorakbar. "Synthesis and Application of Bis[1,2-(4-aryl-2-alkyl-1H- inden-1-yl)]Ethane as an Efficient`Ligand for Preparation of Olefin Polymerization Catalysts". , 30, 2, 1398, 135-142. doi: 10.22059/jsciences.2019.71749
Lotfi, v., Emamgholi, B., Bahrami, S. T., poorakbar, E.. (1398). 'Synthesis and Application of Bis[1,2-(4-aryl-2-alkyl-1H- inden-1-yl)]Ethane as an Efficient`Ligand for Preparation of Olefin Polymerization Catalysts', , 30(2), pp. 135-142. doi: 10.22059/jsciences.2019.71749
Lotfi, v., Emamgholi, B., Bahrami, S. T., poorakbar, E.. Synthesis and Application of Bis[1,2-(4-aryl-2-alkyl-1H- inden-1-yl)]Ethane as an Efficient`Ligand for Preparation of Olefin Polymerization Catalysts. , 1398; 30(2): 135-142. doi: 10.22059/jsciences.2019.71749

Synthesis and Application of Bis[1,2-(4-aryl-2-alkyl-1H- inden-1-yl)]Ethane as an Efficient`Ligand for Preparation of Olefin Polymerization Catalysts

Journal of Sciences, Islamic Republic of Iran
مقاله 5، دوره 30، شماره 2، تیر 2019، صفحه 135-142    اصل مقاله (184.67 K)
نوع مقاله: Original Paper
شناسه دیجیتال (DOI): 10.22059/jsciences.2019.71749
نویسندگان
v. Lotfi* 1؛ B. Emamgholi2؛ S. T. Bahrami3؛ E. poorakbar* 4
1Department of Chemistry, Faculty of Sciences, University of Tehran, Tehran, Islamic Republic of Iran
2Department of Chemistry, Faculty of Sciences, Imam Khomeini International University, Qazvin, Islamic Republic of Iran
3Department of Chemistry, Faculty of Sciences, Islamic Azad University, Qaemshahr Branch, Qaemshahr, Islamic Republic of Iran
4Department of Biology, Faculty of Sciences,University of Payame Noor, Tehran, Islamic Republic of Iran
چکیده
In this study, a class of bis-1,2-(4-aryl-2-alkyl-1H- inden-1-yl) ethane was synthesized and characterized by spectroscopic methods such as 1HNMR, 13CNMR, melting point and FTIR. bis-1,2-(4-aryl-2-alkyl-1H- inden-1-yl) ethane was synthesized by the reaction of butyl­lithium, arylindenes and dibromoethane in a facile, one-pot strategy. It’s shown that these methods have a wide scope to afford libraries of aryl-substituted indenes. The prepared compounds was then applied as a ligand for the fabrication of a number of metal complexes which can be used as catalyst for the polymerization of the olefins.
کلیدواژه‌ها
Organometallic Compound؛ Metallocene؛ Bis-arylalkyl Ethane Ligand؛ Catalysis
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