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Sheykholeslami, Seyed Omid Reza, Etminanfar, Mohamadreza, Khalil-Allafi, Jafar. (1399). Toward a facile synthesis of spherical sub-micron mesoporous silica: Effect of surfactant concentration. , 53(1), 31-38. doi: 10.22059/jufgnsm.2020.01.05
Seyed Omid Reza Sheykholeslami; Mohamadreza Etminanfar; Jafar Khalil-Allafi. "Toward a facile synthesis of spherical sub-micron mesoporous silica: Effect of surfactant concentration". , 53, 1, 1399, 31-38. doi: 10.22059/jufgnsm.2020.01.05
Sheykholeslami, Seyed Omid Reza, Etminanfar, Mohamadreza, Khalil-Allafi, Jafar. (1399). 'Toward a facile synthesis of spherical sub-micron mesoporous silica: Effect of surfactant concentration', , 53(1), pp. 31-38. doi: 10.22059/jufgnsm.2020.01.05
Sheykholeslami, Seyed Omid Reza, Etminanfar, Mohamadreza, Khalil-Allafi, Jafar. Toward a facile synthesis of spherical sub-micron mesoporous silica: Effect of surfactant concentration. , 1399; 53(1): 31-38. doi: 10.22059/jufgnsm.2020.01.05

Toward a facile synthesis of spherical sub-micron mesoporous silica: Effect of surfactant concentration

Journal of Ultrafine Grained and Nanostructured Materials
دوره 53، شماره 1، شهریور 2020، صفحه 31-38    اصل مقاله (2.65 M)
نوع مقاله: Research Paper
شناسه دیجیتال (DOI): 10.22059/jufgnsm.2020.01.05
نویسندگان
Seyed Omid Reza Sheykholeslami؛ Mohamadreza Etminanfar* ؛ Jafar Khalil-Allafi
Research Center for Advanced Materials, Faculty of Materials Engineering, Sahand University of Technoloy, Tabriz, Iran.
چکیده
In this paper, a facile method for preparing sub-micron spherical mesoporous silica by the sol-gel process and cationic surfactant cetyltrimethylammonium bromide (CTAB) as a soft template was reported. Moreover, the effect of surfactant concentration on the specific surface area and the total pore volume was investigated. The specific surface area, pore characteristic, morphology, chemical composition, and structure of mesoporous silica were studied using various methods. The N2 adsorption test showed that increasing the CTAB concentration from 4.6 mM to 7.2 mM increases the specific surface area from 416.48 to 564.07 m2g-1. However, the maximum pore volume was obtained at 5.9 mM CTAB. The spherical shape of the powders was confirmed by field emission scanning electron microscopy. Besides, X-ray diffraction, fourier transform infrared spectra, and energy dispersive spectrometry analysis indicated that the synthesized samples are SiO2, with an amorphous structure. Based on the structure and properties of obtained synthesized mesoporous silica, it is a good candidate for a drug reservoir and the carrier for new controlled drug delivery systems. 
کلیدواژه‌ها
Mesoporous؛ Silica؛ Surfactant؛ CTAB؛ Specific surface area؛ Pore volume
مراجع

1. Vallet-Regí M, Balas F, Arcos D. Mesoporous Materials for Drug Delivery. Angewandte Chemie International Edition. 2007;46(40):7548-58.

2. Vallet-Regí M. Ordered Mesoporous Materials in the Context of Drug Delivery Systems and Bone Tissue Engineering. Chemistry - A European Journal. 2006;12(23):5934-43.

3. Wang Y, Zhao Q, Han N, Bai L, Li J, Liu J, et al. Mesoporous silica nanoparticles in drug delivery and biomedical applications. Nanomedicine: Nanotechnology, Biology and Medicine. 2015;11(2):313-27.

4. Scott BJ, Wirnsberger G, Stucky GD. Mesoporous and Mesostructured Materials for Optical Applications. Chemistry of Materials. 2001;13(10):3140-50.

5. Li W, Liu J, Zhao D. Mesoporous materials for energy conversion and storage devices. Nature Reviews Materials. 2016;1(6).

6. Corma A, Moliner M, Díaz-Cabañas MJ, Serna P, Femenia B, Primo J, et al. Biomimetic synthesis of microporous and mesoporous materials at room temperature and neutral pH, with application in electronics, controlled release of chemicals, and catalysis. New Journal of Chemistry. 2008;32(8):1338.

7. Vallet-Regí M, Ruiz-González L, Izquierdo-Barba I, González-Calbet JM. Revisiting silica based ordered mesoporous materials: medical applications. J Mater Chem. 2006;16(1):26-31.

8. Giri S, Trewyn BG, Lin VSY. Mesoporous silica nanomaterial-based biotechnological and biomedical delivery systems. Nanomedicine. 2007;2(1):99-111.

9. Ariga K, Vinu A, Yamauchi Y, Ji Q, Hill JP. Nanoarchitectonics for Mesoporous Materials. Bulletin of the Chemical Society of Japan. 2012;85(1):1-32.

10. Soler-Illia GJAA, Azzaroni O. Multifunctional hybrids by combining ordered mesoporous materials and macromolecular building blocks. Chemical Society Reviews. 2011;40(2):1107.

11. Liu J, Qiao SZ, Hu QH, Max Lu GQ. Magnetic Nanocomposites with Mesoporous Structures: Synthesis and Applications. Small. 2011;7(4):425-43.

12. Ciesla U, Schüth F. Ordered mesoporous materials. Microporous and Mesoporous Materials. 1999;27(2-3):131-49.

13. Bao Y, Shi C, Wang T, Li X, Ma J. Recent progress in hollow silica: Template synthesis, morphologies and applications. Microporous and Mesoporous Materials. 2016;227:121-36.

14. Farjadian F, Roointan A, Mohammadi-Samani S, Hosseini M. Mesoporous silica nanoparticles: Synthesis, pharmaceutical applications, biodistribution, and biosafety assessment. Chemical Engineering Journal. 2019;359:684-705.

15. Pal N, Bhaumik A. Soft templating strategies for the synthesis of mesoporous materials: Inorganic, organic–inorganic hybrid and purely organic solids. Advances in Colloid and Interface Science. 2013;189-190:21-41.

16. Ying JY, Mehnert CP, Wong MS. Synthesis and Applications of Supramolecular-Templated Mesoporous Materials. Angewandte Chemie International Edition. 1999;38(1-2):56-77.

17. Wan Y, Zhao. On the Controllable Soft-Templating Approach to Mesoporous Silicates. Chemical Reviews. 2007;107(7):2821-60.

18. Vartuli JC, Kresge CT, Leonowicz ME, Chu AS, McCullen SB, Johnson ID, et al. Synthesis of Mesoporous Materials: Liquid-Crystal Templating versus Intercalation of Layered Silicates. Chemistry of Materials. 1994;6(11):2070-7.

19. Slowing I, Viveroescoto J, Wu C, Lin V. Mesoporous silica nanoparticles as controlled release drug delivery and gene transfection carriers☆. Advanced Drug Delivery Reviews. 2008;60(11):1278-88.

20. Vivero-Escoto JL, Slowing II, Trewyn BG, Lin VSY. Mesoporous Silica Nanoparticles for Intracellular Controlled Drug Delivery. Small. 2010;6(18):1952-67.

21. Vallet-Regi M, Rámila A, del Real RP, Pérez-Pariente J. A New Property of MCM-41:  Drug Delivery System. Chemistry of Materials. 2001;13(2):308-11.

22. Shi X, Wang Y, Wei K, Ren L, Lai C. Self-assembly of nanohydroxyapatite in mesoporous silica. Journal of Materials Science: Materials in Medicine. 2008;19(8):2933-40.

23. Croissant JG, Fatieiev Y, Khashab NM. Degradability and Clearance of Silicon, Organosilica, Silsesquioxane, Silica Mixed Oxide, and Mesoporous Silica Nanoparticles. Advanced Materials. 2017;29(9):1604634.

24. Yang Y, Li J. Silica-based Nanostructured Porous Biomaterials. Advanced Topics in Science and Technology in China: Springer Berlin Heidelberg; 2010. p. 1-30.

25. Li X, Garamus VM, Li N, Gong Y, Zhe Z, Tian Z, et al. Preparation and characterization of a pH-responsive mesoporous silica nanoparticle dual-modified with biopolymers. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2018;548:61-9.

26. Martínez-Carmona M, Lozano D, Colilla M, Vallet-Regí M. Lectin-conjugated pH-responsive mesoporous silica nanoparticles for targeted bone cancer treatment. Acta Biomaterialia. 2018;65:393-404.

27. Rosenholm JM, Zhang J, Sun W, Gu H. Large-pore mesoporous silica-coated magnetite core-shell nanocomposites and their relevance for biomedical applications. Microporous and Mesoporous Materials. 2011;145(1-3):14-20.

28. Hu Q, Li Y, Zhao N, Ning C, Chen X. Facile synthesis of hollow mesoporous bioactive glass sub-micron spheres with a tunable cavity size. Materials Letters. 2014;134:130-3.

29. Hwang N, Barron AR. BET surface area analysis of nanoparticles. The Connexions project. 2011:1-1.

30. Zheng X, Zhang J, Wang J, Qi X, Rosenholm JM, Cai K. Polydopamine Coatings in Confined Nanopore Space: Toward Improved Retention and Release of Hydrophilic Cargo. The Journal of Physical Chemistry C. 2015;119(43):24512-21.

31. Oliveira DM, Andrada AS. Synthesis of ordered mesoporous silica MCM-41 with controlled morphology for potential application in controlled drug delivery systems. Cerâmica. 2019;65(374):170-9.

32. Thommes M, Kaneko K, Neimark AV, Olivier JP, Rodriguez-Reinoso F, Rouquerol J, et al. Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure and Applied Chemistry. 2015;87(9-10):1051-69.

33. Tabia Z, El Mabrouk K, Bricha M, Nouneh K. Mesoporous bioactive glass nanoparticles doped with magnesium: drug delivery and acellular in vitro bioactivity. RSC Advances. 2019;9(22):12232-46.

34. Lu B, Kawamoto K. A novel approach for synthesizing ordered mesoporous silica SBA-15. Materials Research Bulletin. 2012;47(6):1301-5.

35. Zhao XS, Lu GQ, Whittaker AK, Millar GJ, Zhu HY. Comprehensive study of surface chemistry of MCM-41 using 29Si CP/MAS NMR, FTIR, pyridine-TPD, and TGA. The Journal of Physical Chemistry B. 1997 Aug 14;101(33):6525-31.

36. Jani AT, Haghighi NB, Sheikh Hossein Pour M, Aminian M, Molzemi S. Hydroxyapatite incorporation into MCM-41 and study of ibuprofen drug release. Journal of the Australian Ceramic Society. 2019;56(2):653-61.

37. Xu H, Ge Y-W, Lu J-W, Ke Q-F, Liu Z-Q, Zhu Z-A, et al. Icariin loaded-hollow bioglass/chitosan therapeutic scaffolds promote osteogenic differentiation and bone regeneration. Chemical Engineering Journal. 2018;354:285-94.

38. Koohkan R, Hooshmand T, Tahriri M, Mohebbi-Kalhori D. Synthesis, characterization and in vitro bioactivity of mesoporous copper silicate bioactive glasses. Ceramics International. 2018;44(2):2390-9.

39. Juère E, Kleitz F. On the nanopore confinement of therapeutic drugs into mesoporous silica materials and its implications. Microporous and Mesoporous Materials. 2018;270:109-19.

40. Wang S. Ordered mesoporous materials for drug delivery. Microporous and Mesoporous Materials. 2009;117(1-2):1-9.

41. Vallet-Regí M. Nanostructured mesoporous silica matrices in nanomedicine. Journal of Internal Medicine. 2010;267(1):22-43.

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