تعداد نشریات | 161 |
تعداد شمارهها | 6,532 |
تعداد مقالات | 70,504 |
تعداد مشاهده مقاله | 124,121,708 |
تعداد دریافت فایل اصل مقاله | 97,229,038 |
Green Synthesis of ZSM-5@rGO Composite for Adsorption of Methylene Blue from Aqueous Solution | ||
Pollution | ||
دوره 8، شماره 4، مهر 2022، صفحه 1308-1324 اصل مقاله (1.16 M) | ||
نوع مقاله: Original Research Paper | ||
شناسه دیجیتال (DOI): 10.22059/poll.2022.342339.1458 | ||
نویسندگان | ||
Xuan Nui Pham* ؛ Hoa Thi Nguyen | ||
Department of Chemical Engineering, Hanoi University of Mining and Geology, 18 Vien Street, Duc Thang Ward, Bac Tu Liem, Hanoi, Vietnam. | ||
چکیده | ||
A green approach was employed to fabricate ZSM-5 zeolite from expanded perlite and reduced graphene oxide (rGO) in the presence of the synthesized ZSM-5 zeolite to produce ZSM-5@rGO composite by one-step synthesis process via hydrothermal treatment. ZSM-5@rGO composites were characterized by various techniques such as scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, Raman spectroscopy, and N2 desorption–adsorption. The results showed that ZSM-5@rGO composite have a large surface area, uniform distribution and orderly crystal form. Moreover, the synthesized composites were evaluated as an adsorbent for removing cationic dye, methylene blue (MB), from an aqueous solution. The influence of factors on the adsorption, such as adsorption time, adsorbent dosage, initial dye concentration, and pH of solution, were investigated. The results of isothermal adsorption showed that the adsorption process was fit for both Langmuir and Freundlich models, and the highest adsorption capacity of ZSM-5@rGO composite for MB dye was 95.87 mg/g at environment temperature (30 oC). In addition, the study of adsorption kinetics indicated that the adsorption was consistent with the pseudo-second-order kinetic model with correlation coefficients of 0.9962. From these results, it can be confirmed that ZSM-5@rGO composite uses silicoaluminate as economical starting material with relatively high adsorption capacity and removal efficiency, which is a promising application for treating wastewater on a large scale. | ||
کلیدواژهها | ||
reduced graphene oxide؛ expanded perlite؛ ZSM-5؛ ZSM-5@rGO؛ MB | ||
مراجع | ||
Abalos, R.; Erdmann, E. and Destefanis, H.A. (2003). Surface modifications of volcanic glasses (perlites) by water vapor. Lat. Am. Appl. Res., 33, 59–62. Bagane, M. and Guiza, S. (2000). Removal of a dye from textile effluents by adsorption. Annales de Chimie-Science des Matériaux, 25, 615–625. Belova, T.P. (2019). Adsorption of heavy metal ions (Cu2+, Ni2+, Co2+ and Fe2+) from aqueous solutions by natural zeolite. Heliyon, 5, e02320. Cadiam, M.B.; Rajangam, V.; Balachandran, S.; Aziz, A.; Mei, M.P.; Wang, S.C. and Hyun-Tae J. (2016). Characterization of reduced graphene oxide supported mesoporous Fe2O3/TiO2 nanoparticles and adsorption of As (III) and As (V) from potable water. J. Taiwan Inst. Chem. Eng., 62, 199–208. Chen, L.; Yang, J.; Zeng, X.; Zhang, L. and Yuan, W. (2013). Adsorption of methylene blue in water by reduced graphene oxide: Effect of functional groups. Mater. Express, 3, 281–290. Chen, N.Y. (1996). Shape selective catalysis in industrial applications, Second Edition. CRC press 65. Choudhury, P.; Chattopadhyay, S.; De, G. and Basu, B. (2021). Ni–rGO–zeolite nanocomposite: an efficient heterogeneous catalyst for one-pot synthesis of triazoles in water. Mater. Adv., 2, 3042–3050. Corregidor, P.F.; Acosta, D.E. and Destéfanis, H.A. (2014). Green synthesis of ZSM-5 zeolite prepared by hydrothermal treatment of perlite. Effect of chemical composition and characterization of the product. Sci. Adv. Mater., 6, 1203–1214. Da Silva Filho, S.H.; Vinaches, P. and Pergher, S.B.C. (2018). Zeolite synthesis in basic media using expanded perlite and its application in Rhodamine B adsorption. Mater. Lett., 227, 258–260. Dai, M. (1998). Mechanism of adsorption for dyes on activated carbon. J. Colloid. Interface Sci., 198, 6–10. Fabian, A.A.; Marco, G.; Talia, T.; Paola, A.; Raul, M.; Andrea, V.; Orlando, S.; Cristian, V.G.; Melvin, A. and Lorenzo, S.C. (2020). The adsorption of methylene blue on eco-friendly reduced graphene oxide. Nanomaterials, 10 (4), 681. Faghihian, H. and Kamali, M. (2003). Synthesis of Na-Pc zeolite from perlite and study of its ability to remove cyanide from liquid wastes. Int. J. Environ. Pollut., 19, 557-566. Fan, W.; Li, R.; Ma, J.; Fan, B. and Cao, J. (1995). Synthesis, characterization and catalytic properties of MFI-type zeolites prepared in the system Na2O−SiO2−Al2O3−H2N(CH2)6NH2−NH4F. Microporous Mater., 4, 301–307. Feng, P.; Xuchen, L.; Qingshan, Z.; Zhimin, Z.; Yan, Y. and Shiwei. (2015). Direct synthesis of HZSM-5 from natural clay. J. Mater. Chem. A., 3, 4058–4066. Filho, S.H.S.; Vinaches, P. and Pergher, S.B.C. (2018). Zeolite synthesis in basic media using expanded perlite and its application in Rhodamine B adsorption. Mater. Lett., 227, 258-260. Gao, W. (2015). The chemistry of graphene oxide. Graphene oxide Springer, 61–95. Gök. Ö.; Özcan, A.S. and Özcan, A. (2010). Adsorption behavior of a textile dye of Reactive Blue 19 from aqueous solutions onto modified bentonite. Appl. Surf. Sci., 256, 5439–5443. Hauchhum, L. and Mahanta, P. (2014). Carbon dioxide adsorption on zeolites and activated carbon by pressure swing adsorption in a fixed bed. Int. J. Energy. Environ. Eng., 5, 349–356. Hernandez, J.M.M.; San German C.M.R.; Arceo, L.D.B.; Villalobos, L.Z. and Flores, M.E. (2013). Synthesis and characterization of carbon nanospheres obtained by microwave radiation. Carbon, 54, 168–174. Hummers, Jr.W.S and Offeman, R.E. (1958). Preparation of graphitic oxide. J. Am. Chem. Soc., 80, 1339. Imamura, K.; Ikeda, E.; Nagayasu, T.; Sakiyama, T. and Nakanishi, K. (2002). Adsorption behavior of methylene blue and its congeners on a stainless steel surface. J. Colloid. Interface Sci., 245, 50-70. Jorge, G.I.; Margarita, H.-E.; Carmen, D.-S.; Arturo, F.-I.; Mono, M.S. (2008). The point of zero charge of oxides. Environ. Chem., 70–78. Khatamian, M.; Khodakarampoor, N.; Oskoui, M.S. and Kazemian, N. (2015). Synthesis and characterization of RGO/zeolite composites for the removal of arsenic from contaminated water. RSC Adv., 5, 35352–35360. Khatamian, M.; Khodakarampoor, N. and Saket-Oskoui, M. (2017). Efficient removal of arsenic using graphene-zeolite based composites. J. Colloid. Interface Sci., 498, 433-441. Kim, D.W.; Han, H.; Kim, H.; Guo, X. and Tsapatsis, M. (2018). Preparation of a graphene oxide/faujasite composite adsorbent. Micropor. Mesopor. Mat., 268, 243–250. Król, M. (2020). Natural vs. synthetic zeolites. Crystals, 10 (7), 622. Li, B.; Cao, H. and Yin, G. (2011). Mg(OH)2@reduced graphene oxide composite for removal of dyes from water. J. Mater. Chem., 21, 13765–13768. Li, D.; Qiu, L.; Wang, K.; Zeng, Y.; Li, D.; Williams, T.; Huang, Y.; Tsapatsis, M.; Wang, H. (2012). Growth of Zeolite Crystals with Graphene Oxide Nanosheets. Chem. Comm., 48 (16), 2249–2251. Liu, Y.; Lu, H. (2020). Synthesis of ZSM-5 zeolite from fly ash and its adsorption of phenol, quinoline and indole in aqueous solution. Mater. Res. Express, 7, 55506. Liu, Y.S.; Jiang, X.Q.; Li, B.J.; Zhang, X.D.; Liu, T.Z.; Yan, X.S.; Ding, J.; Cai, Q. and Zhang, J.M. (2014). Halloysite nanotubes@reduced graphene oxide composite for removal of dyes from water and as supercapacitors. J. Mater. Chem. A., 2, 4264-4269. Luo, P.; Zhao, Y.; Zhang, B.; Liu, J.; Yang, Y. and Liu, J. (2010). Study on the adsorption of Neutral Red from aqueous solution onto halloysite nanotubes. Water Res., 44 (5), 1489-97. Magdalena, K.; Justyna, M.; Włodzimierz, M. and Waldemar, P. (2014). Low-temperature synthesis of zeolite from perlite waste – Part II: characteristics of the products. Mater. Sci.-Pol., 32, 526 - 532 Mei, X.; Meng, X. and Wu, F. (2015). Hydrothermal method for the production of reduced graphene oxide. Phys. E Low-Dimens. Syst. Nanostruct., 68, 81–86. Navrotsky, A. (1994). Thermochemistry of crystalline and amorphous silica. Rev. Mineral. Geochem., 29, 309–329. Pathania, D.; Sharma, S. and Singh, P. (2017). Removal of methylene blue by adsorption onto activated carbon developed from Ficus carica bast. Arab. J. Chem., 10, S1445–S1451. Prasun, C.; Shreyasi, C.; Goutam, D.; Basudeb, B. (2021). Ni–rGO–zeolite nanocomposite: an efficient heterogeneous catalyst for one-pot synthesis of triazoles in water. Mater. Adv., 2 (9), 3042–3050. Ramesha, G.K.; Kumara, A.V.; Muralidharam, H.B. and Sampath, S. (2011). Graphene and graphene oxide as effective adsorbents toward anionic and cationic dyes. J. Colloid. Interface Sci., 361, 270–277. Sismanoglu, T.; Kismir, Y. and Karakus, S. (2010). Single and binary adsorption of reactive dyes from aqueous solutions onto clinoptilolite. J. Hazard. Mater., 184, 164–169. Sourav, S.; Tapas, K.G.; Dipak, R.; Indranil, R.; Amarty, B.; Gunjan, S.; Mukut, C. and Dipankar, C. (2016). Studies on synthesis of reduced graphene oxide (RGO) via green route and its electrical property. Mater. Res. Bull., 79, 41–51. Taddeo, R.; Prajapati, S. and Lepistö, R. (2017). Optimizing ammonium adsorption on natural zeolite for wastewaters with high loads of ammonium and solids. J. Porous Mater., 24, 1545–1554. Tan, T.V.; Vinh, T.L.; Tuan, V.P.; Giang, T.V. (2022). The highly efficient purification capacity of rGO-zeolite composites for aged oil in transformer machines. Arab. J. Chem., 15 (3), 103683. Uddin, M.T.; Islam, M.A.; Mahmud, S. and Rukanuzzaman, M. (2009). Adsorptive removal of methylene blue by tea waste. J. Hazard. Mater., 164, 53–60. Vu, T.T.; La, T.V.; Pham, V. T..; Minh Khoi, V.; Huynh, D.C. and Tran, N.K. 2020. Highly Efficient Adsorbent for the Transformer Oil Purification by ZnO/Graphene Composite. Arab. J. Chem., 13 (11), 7798–7808. Vuong, H.N.T.; Anh, T.N.T.; Van, D.H.V.; Cuong, N.D.; Khieu, D.Q and Vo, V. (2016). Fe3O4/reduced graphene oxide nanocomposite: synthesis and its application for toxic metal ion removal. J. Chem., 2016, 10 pages. Vuong, H.T.N.; Minh, N.N.; Tam, T.T.; Tien, T.N.; Huan, V.D and Xuan, N.P. (2020). One-pot preparation of alumina-modified polysulfone-graphene oxide nanocomposite membrane for separation of emulsion-oil from wastewater. J. Nanomater., 2020, 12 pages. Wang, Y.; Feng, R.; Li, X.; Liu, X. and Yan, Z. (2013). In situ synthesis, characterization and catalytic activity of ZSM-5 zeolites on kaolin microspheres from amine-free system. J. Porous Mater., 20, 137–141. Xuan, N.P.; Hoa, T.N.; Nhung, T.P.; Bao, T.T.N.; Manh, B.N.; Thi, V.T.T.; Huan, V.D. (2020). Green synthesis of H-ZSM-5 zeolite-anchored O-doped g-C3N4 for photodegradation of Reactive Red 195 (RR 195) under solar light. J. Taiwan Inst. Chem. Eng., 114, 91–102. Yang, Z.; Ji, S.; Gao, W.; Zhang, C.; Ren, L.; Tjiu, W.W.; Zhang, Z.; Pan, J. and Liu, T. (2013). Magnetic nanomaterial derived from graphene oxide/layered double hydroxide hybrid for efficient removal of methyl orange from aqueous solution. J. Colloid. Interface Sci., 408, 25–32. Yushan, L.; Xiaoqing, J.; Baojun, L.; Xudong, Z.; Tiezhu L.; Xiaoshe, Y.; Jie, D.; Qiang C. and Jianmin, Z. (2014). Halloysite nanotubes@reduced graphene oxide composite for removal of dyes from water and as supercapacitors. J. Mater. Chem. A., 12, 4264–4269. Zhang, W.; Wang, K,; Yu, Y. and He, H. (2010). TiO2/HZSM-5 nano-composite photocatalyst: HCl treatment of NaZSM-5 promotes photocatalytic degradation of methyl orange. Chem. Eng. J., 163, 62–67. | ||
آمار تعداد مشاهده مقاله: 633 تعداد دریافت فایل اصل مقاله: 634 |