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بررسی پدیده پسماند سیپروفلوکساسین در خاک | ||
| تحقیقات آب و خاک ایران | ||
| دوره 54، شماره 10، دی 1402، صفحه 1597-1608 اصل مقاله (1.5 M) | ||
| نوع مقاله: مقاله پژوهشی | ||
| شناسه دیجیتال (DOI): 10.22059/ijswr.2023.364096.669554 | ||
| نویسندگان | ||
| ماهرخ شریف مند1؛ ابراهیم سپهر* 2؛ میرحسن رسولی صدقیانی3؛ سیامک عصری رضایی4 | ||
| 1گروه علوم خاک، دانشکده کشاورزی، دانشگاه ارومیه، ارومیه، ایران. | ||
| 2گروه علوم خاک، دانشکده کشاورزی، دانشگاه ارومیه، ارومیه، ایران | ||
| 3گروه علوم خاک، دانشکده کشاورزی، دانشگاه ارومیه، ارومیه ایران | ||
| 4گروه علوم درمانگاهی، دانشکده دامپزشکی، دانشگاه ارومیه، ارومیه، ایران، | ||
| چکیده | ||
| آنتی‌بیوتیک‌ها به عنوان آلاینده‌های نو ظهور تاثیر بالقوه‌ای بر محیط زیست و سلامت انسان دارند و ورود آن‌ها به محیط زیست نگرانی‌های زیادی را ایجاد کرده است. برای مطالعه پدیده پسماند سیپروفلوکساسین در خاک، فرایند جذب با غلظت‌های مختلف سیپروفلوکساسین (صفر تا یک mmol L-1) در یک نمونه خاک آهکی انجام و سپس برگشت پذیری فرآیند جذب از طریق آزمایش‌های واجذب نمونه‌های خاک آلوده به سیپروفلوکساسین ارزیابی شد. غلظت سیپروفلوکساسین با استفاده از دستگاه کروماتوگرافی مایع با کارایی بالا (HPLC-MS/MS) تعیین شد. داده‌های حاصل از آزمایش با معادلات لانگمویر، فروندلیچ و ردلیچ-پترسون برازش داده شدند. مدل ردلیچ-پترسون با کمترین میزان خطا (۲۴/۰SE=) و بیشترین ضریب همبستگی (۹۹/۰= R2) داده‌های تعادلی را به خوبی توصیف کرد. مقدار عددی توان این معادله (g) کمتر از یک و در نتیجه سطوح جذب ناهمگن می‌باشد. جذب سیپروفلوکساسین با افزایش غلظت اولیه آنتی‌بیوتیک در خاک افزایش یافت، به طوری که بالاترین راندمان جذب و واجذب سیپروفلوکساسین در غلظت یک mmol L-1 به ترتیب ۹۶ و ۲ درصد بود. ضریب هیسترسیس ۸۹/۰ به دست آمد که نشان‌دهنده برگشت‌پذیری کم فرایند جذب یا پدیده پسماند است. اتصال محکم آنتی‌بیوتیک سیپروفلوکساسین به اجزای خاک منجر به تجزیه پذیری پایین و پایداری این آلاینده آلی در محیط خاک می‌گردد. | ||
| کلیدواژه‌ها | ||
| آنتی‌بیوتیک؛ برگشت پذیری؛ پسماند؛ جذب؛ واجذب | ||
| عنوان مقاله [English] | ||
| Study of the Ciprofloxacin hysteresis phenomenon in soil | ||
| نویسندگان [English] | ||
| Mahrokh Sharifmand1؛ Ebrahim Sepehr2؛ MirHassan Rasouli-Sadaghiani3؛ Siamak Asri-Rezaei4 | ||
| 1Department of Soil Science, Faculty of Agriculture, Urmia University, Urmia, Iran | ||
| 2Department of Soil Science, Faculty of Agriculture, Urmia University, Urmia, Iran | ||
| 3Department of Soil Science, Faculty of Agriculture, Urmia University, Urmia, Iran | ||
| 4Department of Clinical Sciences, Faculty of Veterinary Medicine, Urmia University, Urmia, Iran. | ||
| چکیده [English] | ||
| Antibiotics as emerging pollutants, potentially affect the environment and human health and their entry into the environment has created great concerns. To study the ciprofloxacin hysteresis phenomenon in the soil, the adsorption process was done with different concentrations of ciprofloxacin (0–1 mmol L-1) on a calcareous soil system. Then, the reversibility of the adsorption process was assessed through desorption experiments of ciprofloxacin-loaded soil samples. The concentration of ciprofloxacin was determined using high-performance liquid chromatography-tandem mass spectrometry (HPLC–MS/MS). The experimental data were analyzed using the Langmuir, Freundlich, and Redlich-Peterson isotherms. The results demonstrated the experimental data followed the Redlich-Peterson isotherm model due to the lowest value of error (SE= 0.24) and the highest value of correlation coefficient (R²=0.99). The exponent value of this equation (g) was less than one, so the adsorption surfaces are heterogeneous. Ciprofloxacin adsorption increased with increasing initial concentrations. The highest adsorption and desorption efficiency of ciprofloxacin was obtained at concentration 1 mmol L-1, 96% and 2%, respectively. The hysteresis index was 0.89 indicating low reversibility of the adsorption process or hysteresis phenomenon. The strong bind of the ciprofloxacin to the soil components leads to less degradability in soil and forms stable residues in the soil environment. | ||
| کلیدواژه‌ها [English] | ||
| Adsorption, Antibiotic, Desorption, Hysteresis, Reversibility | ||
| مراجع | ||
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