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Abbasi, Alireza, Tavakkoli, Saeideh, Hosseini, Mahdiyeh-Sadat. (1403). From The Rational Design of Cobalt-zinc Bimetallic MOF to Catalytic Behavior in Knoevenagel Condensation Reaction. , 35(1), 15-23. doi: 10.22059/jsciences.2024.376401.1007864
Alireza Abbasi; Saeideh Tavakkoli; Mahdiyeh-Sadat Hosseini. "From The Rational Design of Cobalt-zinc Bimetallic MOF to Catalytic Behavior in Knoevenagel Condensation Reaction". , 35, 1, 1403, 15-23. doi: 10.22059/jsciences.2024.376401.1007864
Abbasi, Alireza, Tavakkoli, Saeideh, Hosseini, Mahdiyeh-Sadat. (1403). 'From The Rational Design of Cobalt-zinc Bimetallic MOF to Catalytic Behavior in Knoevenagel Condensation Reaction', , 35(1), pp. 15-23. doi: 10.22059/jsciences.2024.376401.1007864
Abbasi, Alireza, Tavakkoli, Saeideh, Hosseini, Mahdiyeh-Sadat. From The Rational Design of Cobalt-zinc Bimetallic MOF to Catalytic Behavior in Knoevenagel Condensation Reaction. , 1403; 35(1): 15-23. doi: 10.22059/jsciences.2024.376401.1007864

From The Rational Design of Cobalt-zinc Bimetallic MOF to Catalytic Behavior in Knoevenagel Condensation Reaction

Journal of Sciences, Islamic Republic of Iran
مقاله 2، دوره 35، شماره 1، خرداد 2024، صفحه 15-23    اصل مقاله (1.02 M)
نوع مقاله: Original Paper
شناسه دیجیتال (DOI): 10.22059/jsciences.2024.376401.1007864
نویسندگان
Alireza Abbasi* 1؛ Saeideh Tavakkoli2؛ Mahdiyeh-Sadat Hosseini3
11 School of Chemistry, College of Science, University of Tehran, Tehran, Islamic Republic of Iran
22 Department of Chemistry, Science and Research Branch, Islamic Azad University, Tehran, Islamic Republic of Iran
33 School of Chemistry, College of Science, University of Tehran, Tehran, Islamic Republic of Iran
چکیده
In this study, a bimetallic Co-Zn metal-organic framework (Co-Zn-MOF) was synthesized through solvothermal conditions by using Co2+ and Zn2+ salts, DABCO and H2BDC as the rigid ligands (DABCO= 1,4-diazabicyclo (2.2.2) octane, H2BDC=Benzene-1,4-dicarboxylic acid). This bimetallic MOF was used as a catalyst for the Knoevenagel condensation reaction and exhibited enhanced catalytic activity compared to its parents' single metal MOFs derived from DABCO and H2BDC precursors (Co-MOF and Zn-MOF) at mild reaction conditions, which could be attributed to the synergistic effect between the metal ions.
کلیدواژه‌ها
Metal-organic framework؛ Bimetal-MOF؛ Heterogeneous catalyst؛ Knoevenagel
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