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Maleki, Basir, Ashraf Talesh, Seyed Siamak. (1401). Optimization of the Sono-Biodiesel in the Attendance of ZnO Nanoparticles, Process Yield Enhancement: Box Behnken Design. , 56(1), 1-14. doi: 10.22059/jchpe.2021.330251.1361
Basir Maleki; Seyed Siamak Ashraf Talesh. "Optimization of the Sono-Biodiesel in the Attendance of ZnO Nanoparticles, Process Yield Enhancement: Box Behnken Design". , 56, 1, 1401, 1-14. doi: 10.22059/jchpe.2021.330251.1361
Maleki, Basir, Ashraf Talesh, Seyed Siamak. (1401). 'Optimization of the Sono-Biodiesel in the Attendance of ZnO Nanoparticles, Process Yield Enhancement: Box Behnken Design', , 56(1), pp. 1-14. doi: 10.22059/jchpe.2021.330251.1361
Maleki, Basir, Ashraf Talesh, Seyed Siamak. Optimization of the Sono-Biodiesel in the Attendance of ZnO Nanoparticles, Process Yield Enhancement: Box Behnken Design. , 1401; 56(1): 1-14. doi: 10.22059/jchpe.2021.330251.1361

Optimization of the Sono-Biodiesel in the Attendance of ZnO Nanoparticles, Process Yield Enhancement: Box Behnken Design

Journal of Chemical and Petroleum Engineering
دوره 56، شماره 1، شهریور 2022، صفحه 1-14    اصل مقاله (1.63 M)
نوع مقاله: Research Paper
شناسه دیجیتال (DOI): 10.22059/jchpe.2021.330251.1361
نویسندگان
Basir Maleki؛ Seyed Siamak Ashraf Talesh*
Department of Chemical Engineering, Faculty of Engineering, University of Guilan, Rasht, Iran
چکیده
The growing fuel demands and drastic restrictions of politics on greenhouse gases emissions are motivating towards bioenergy research. In this paper, the yield improvement of the produced biodiesel from canola oil using transesterification process, in attendance of ZnO nanocatalyst and ultrasound waves, was investigated. The crystal size, morphology, and particle size of the prepared nanoparticles were recognized applying X-ray diffraction (XRD), scanning electron microscopy (SEM) and transverse electron microscopy (TEM) analyses, respectively. The size of ZnO nanoparticles was 45 nm with a hexagonal-shaped structure. The response surface methodology (RSM) and the Box Behnken design (BBD) were employed to analyze the impact of the independent variables on biodiesel production yield. The reliability of the proposed model was verified by applying the analysis of variance (ANOVA) with the objective of evaluating response. Regarding the yield, satisfactory accordance was obtained between the calculated and prognosticated data from RSM, with R2= 0.9910 and R2 adj= 0.9748. The optimum reaction conditions were acquired at methanol to oil molar ratio of 11.19:1 mol: mol, ultrasound irradiation time of 31.98 min, and nanocatalyst amount of 3.17 wt.%. The optimum value for the sono-biodiesel yield was achieved equal to 90.16%. Moreover, the kinetic study exhibited that the values of activation energy and Arnius frequency factor were achieved 46.23 kJ mol-1 and 5.83× 105 min-1, respectively. Accordingly, this research indicated that ZnO nanoparticles can be utilized as a promising and efficient heterogeneous catalyst for biodiesel production.
کلیدواژه‌ها
Biodiesel؛ Heterogeneous Catalyst؛ Kinetic؛ Optimization؛ Ultrasonication؛ ZnO Nanoparticles
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